Basic hydrolysis of glyceryl nitrate esters. II. 1,2‐glyceryl and 1, 3‐glyceryl dinitrate esters

Capellos, C.; Fisco, W. J.; Ribaudo, Cristina; Hogan, Virginia D.; Campisi, Judith; Murphy, F. X.; Castorina, Thomas C.; Rosenblatt, David H.

doi:10.1002/kin.550160807

Cited by 9 publications

(1 citation statement)

References 16 publications

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“…41 kcal/mol . Under strong alkaline conditions, they are susceptible to hydrolysis (S N 2 nucleophilic substitution to give alcohol and nitrate), β-H elimination (forming alkene), and α-H elimination (producing aldehyde and nitrite). , …”

Section: Physical Propertiesmentioning

confidence: 99%

Nitric Oxide Donors: Chemical Activities and Biological Applications

et al. 2002

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Section: Physical Propertiesmentioning

confidence: 99%

Nitric Oxide Donors: Chemical Activities and Biological Applications

et al. 2002

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Basic hydrolysis of glyceryl nitrate esters. III. Trinitroglycerin

Capellos

Fisco

Ribaudo

et al. 1984

Int J of Chemical Kinetics

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Kinetics of the basic hydrolysis of glyceryl trinitrate (TNG) were investigated in C0,-free aqueous calcium hydroxide solutions. The hydrolysis reactions were carried out in a temperature controlled reactor vessel with provision for continuous N, sparging of the reaction mixture. TNG hydrolyzed via second-order reaction at 25"C, 18"C, and 10°C. The activation energy of the hydrolysis reaction of TNG was calculated from the kinetic data and found to be equal to 27.53 kcal/mol. The major products of the hydrolysis of TNG in solution of calcium hydroxide were calcium nitrate and calcium nitrite, accounting for approximately 50% of the degradation products. The minor identified products such as calcium oxalate and nitrate esters amounted to approximatey 6% of the products. The remaining 30% of the isolated products was a mixture of calcium formate, a nitrate ester, and unidentified volatiles, polymerlike substances, and other organic residue.

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Thermal Decomposition of Energetic Materials 69. Analysis of the kinetics of nitrocellulose at 50 °C–500 °C

Brill

Gongwer

1997

Propellants Explo Pyrotec

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Kinetic constants for decomposition of nitrocellulose in the 50 °C to 500°C range are analyzed. At T < 100°C, three processes (depolymerization, peroxide formation, and hydrolysis) are consistent with the reported kinetics. For T = 100°C–200°C, 28 of 30 previously reported kinetic measurements can be organized clearly into two categories by the use of the kinetic compensation effect. These two groups fit the first‐order and autocatalytic processes. Conflicting interpretations are reconciled by this approach. At T > 200°C, the kinetics are consistent with the existence of the first‐order step and desorption of the products as two parallel processes which, together, control the rate. Time‐to‐exotherm and mass burning rate kinetics are compared as temperature‐dependent reaction‐desorption events.

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Basic hydrolysis of glyceryl nitrate esters. II. 1,2‐glyceryl and 1, 3‐glyceryl dinitrate esters

Cited by 9 publications

References 16 publications

Nitric Oxide Donors: Chemical Activities and Biological Applications

Nitric Oxide Donors: Chemical Activities and Biological Applications

Basic hydrolysis of glyceryl nitrate esters. III. Trinitroglycerin

Thermal Decomposition of Energetic Materials 69. Analysis of the kinetics of nitrocellulose at 50 °C–500 °C

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