2013
DOI: 10.1063/1.4809575
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Bandgap tuning in highly c-axis oriented Zn1−xMgxO thin films

Abstract: We propose Mg doping in zinc oxide (ZnO) films for realizing wider optical bandgap in highly c-axis oriented Zn1−xMgxO (0 ≤ x ≤ 0.3) thin films. A remarkable enhancement of 25% in the bandgap by 30% Mg doping was achieved. The bandgap was tuned between 3.25 eV (ZnO) and 4.06 eV (Zn0.7Mg0.3O), which was further confirmed by density functional theory based wien2k simulation employing a combined generalized gradient approximation with scissor corrections. The change of stress and crystallite size in these films w… Show more

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Cited by 98 publications
(39 citation statements)
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“…The values of the strain are listed in Table 1. The average crystallite size (D) was calculated from the full width at half maximum (FWHM) of (311) peak by using Scherer's equation [16] …”
Section: Resultsmentioning
confidence: 99%
“…The values of the strain are listed in Table 1. The average crystallite size (D) was calculated from the full width at half maximum (FWHM) of (311) peak by using Scherer's equation [16] …”
Section: Resultsmentioning
confidence: 99%
“…This absorption band has a wavelength region of 280-340 nm, which is shorter than the absorption region (360-400 nm) of ZnO. Thus, the one absorption band (280-340 nm) is an absorption result of the Mg x Zn 1-x O layer with Mg content (x value) less than 0.3 for the as-deposited Mg x Zn 1-x O [10,11,30].…”
Section: Resultsmentioning
confidence: 99%
“…The large exciton binding energy (60 meV, more than twice that of GaN), of ZnO makes it preferred material over other transparent conductive oxides [5]. Apart from this, ZnO is a very promising because its thin films can be prepared at relatively lower temperature by several growth techniques such as solgel method, sputtering, e-beam or atomic layer deposition (ALD) [6][7][8][9]. Low temperature (LT) ZnO can also be grown using molecular beam epitaxy (MBE), but growth temperatures used there are at the level of 350-500 o C [10,11], which is outside the low thermal budget of crossbar memories or organic electronics.…”
Section: Introductionmentioning
confidence: 98%