2009
DOI: 10.1039/b800312m
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Abstract: Hydrogen storage for transportation applications requires high volumetric and gravimetric storage capacity. B-N compounds are well suited as storage materials due to their light weight and propensity for bearing multiple protic (N-H) and hydridic (B-H) hydrogens. This critical review briefly covers the various methods of hydrogen storage, and then concentrates on chemical hydrogen storage using B-N compounds. The simplest B-N compound, ammonia borane (H3NBH3), which has a potential 19.6 wt% hydrogen storage ca… Show more

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Cited by 1,006 publications
(678 citation statements)
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References 149 publications
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“…More detailed reviews of the properties of chemicals hydrides, with an emphasis on ammonia borane, are available elsewhere. 74,75 Materials synthesis and processing Of course, for any material in the above four classes to form part of a practical hydrogen storage system, techniques must be available to synthesize and process the material. These techniques may only exist on a laboratory scale for research purposes, but ultimately must be capable of low-cost scaling to large volumes for a commercial vehicle application.…”
Section: Chemical Hydridesmentioning
confidence: 99%
See 1 more Smart Citation
“…More detailed reviews of the properties of chemicals hydrides, with an emphasis on ammonia borane, are available elsewhere. 74,75 Materials synthesis and processing Of course, for any material in the above four classes to form part of a practical hydrogen storage system, techniques must be available to synthesize and process the material. These techniques may only exist on a laboratory scale for research purposes, but ultimately must be capable of low-cost scaling to large volumes for a commercial vehicle application.…”
Section: Chemical Hydridesmentioning
confidence: 99%
“…Additionally, a great deal of progress is currently being made in identifying energy-efficient means for the regeneration of ammonia borane. 67,71,74,92 …”
Section: Efficiencymentioning
confidence: 99%
“…[1][2][3][4][5] Metal octahydrotriborates (M(B 3 H 8 ) n ), sometimes known as metal triboranes, have therefore aroused attention. [6][7][8] 2 , has shown a cycling capacity of 2.5 wt %.…”
Section: Introductionmentioning
confidence: 99%
“…Boron-nitrogen containing compounds are expected to find applications in hydrogen storage materials because of their high hydrogen density [6,7]. In particular, ammonia borane (NH 3 BH 3 ) has attracted a great deal of attention due to its high hydrogen content (19.6 wt%), low molecular weight (30.9 g/mol), and high stability [8][9][10][11][12]. Additionally, NH 3 BH 3 releases hydrogen via a hydrolysis reaction in the presence of suitable acids and catalysts at room temperature (Eq.…”
Section: Introductionmentioning
confidence: 99%