Assessment of anthropogenic pollution by UV filters using macrophytes as bioindicators

Cadena-Aizaga, M. Isabel; Montesdeoca-Esponda, Sarah; Santana-del-Pino, Ángelo; Sosa‐Ferrera, Zoraida; Santana‐Rodríguez, José Juan

doi:10.1016/j.scitotenv.2022.155012

Cited by 4 publications

(13 citation statements)

References 24 publications

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“…In this context, PNECs were exceeded at 9 sites for 4-MBC and 4 sites for BP-3. Furthermore, it is important to consider that OUVF concentrations can be higher in biota than observed in water samples due to bioconcentration (Cadena-Aizaga et al 2022 ), and that the toxic effects of OUVF mixtures can occur at concentrations lower than observed for a single chemical (Escher and Hermens 2002 ). To this end, of the four OUVFs detected in this study, two or more were detected in 15 water samples, and in particular, OCT’s high log K ow (> 6) indicates its potential for bioaccumulation (Cadena-Aizaga et al 2022 ).…”

Section: Resultsmentioning

confidence: 99%

“…Furthermore, it is important to consider that OUVF concentrations can be higher in biota than observed in water samples due to bioconcentration (Cadena-Aizaga et al 2022 ), and that the toxic effects of OUVF mixtures can occur at concentrations lower than observed for a single chemical (Escher and Hermens 2002 ). To this end, of the four OUVFs detected in this study, two or more were detected in 15 water samples, and in particular, OCT’s high log K ow (> 6) indicates its potential for bioaccumulation (Cadena-Aizaga et al 2022 ). Results from this study indicate that the potential risk posed by 4-MBC, OCT, and BP-3 to Port Philip Bay aquatic ecosystems are appreciable, and further assessments of their occurrence in PPB and associated biota are paramount to evaluating their ecological risk.…”

Section: Resultsmentioning

confidence: 99%

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Salting-out assisted liquid–liquid extraction combined with LC–MS/MS for the simultaneous determination of seven organic UV filters in environmental water samples: method development and application

Carve,

Singh,

Askeland

et al. 2023

Environ Sci Pollut Res

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Organic UV filters (OUVFs), the active ingredient in sunscreens, are of environmental concern due to reported ecotoxicological effects in aquatic biota. Determining the environmental concentrations of these chemicals is essential for understanding their fate and potential environmental risk. Salting‐out assisted liquid–liquid extraction (SALLE) coupled with liquid-chromatography tandem mass spectrometry (LC–MS/MS) was developed for simultaneous extraction, separation, and quantification of seven OUVFs (2,4-dihydroxybenzophenone, 2,2′,4,4′-tetrahydroxybenzophenone, 4-methylbenzylidene camphor, butyl-methoxy-dibenzoyl methane, octocrylene, octyl methoxycinnamate, and oxybenzone). Method detection limits (MDLs) ranged from 11 to 45 ng/L and practical quantification limits (PQLs) from 33 to 135 ng/L. Method trueness, evaluated in terms of recovery, was 69–127%. Inter-day and intra-day variability was < 6% RSD. The coefficients of determination were > 0.97. The method was applied to river and seawater samples collected at 19 sites in and near Port Phillip Bay, Australia, and temporal variation in OUVF concentrations was studied at two sites. Concentrations of OUVF were detected at 10 sites; concentrations of individual OUVFs were 51–7968 ng/L, and the maximum total OUVF concentration detected at a site was 8431 ng/L. Recreational activity and water residence time at the site contributed to OUVF’s environmental presence and persistence. The benefits of the SALLE-LC–MS/MS method include its simple operation, good selectivity, precision over a wide linear range, and that obtained extracts can be directly injected into the LC–MS/MS, overall making it an attractive method for the determination of these OUVFs in environmental water matrices. To our knowledge, this is the first report of the occurrence of OUVFs in Port Phillip Bay, Australia.

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Section: Resultsmentioning

confidence: 99%

Section: Resultsmentioning

confidence: 99%

Salting-out assisted liquid–liquid extraction combined with LC–MS/MS for the simultaneous determination of seven organic UV filters in environmental water samples: method development and application

Carve,

Singh,

Askeland

et al. 2023

Environ Sci Pollut Res

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“…A microwave-assisted extraction (MAE), followed by LC-MS/MS, was applied to the analysis of BP-3 and other UVFs in macrophytes (seaweeds and seagrass) collected from three different beaches on Gran Canaria Island (Spain) [64]. Determination was performed by a UHPLC system equipped with a C18 column (50 × 2.1 mm, 1.7 µm) and an MS/MS detector in PI.…”

Section: Biota Marine Matricesmentioning

confidence: 99%

“…In two distinguished studies by Cadena-Aizaga et al, the presence of AVO in seawater [56] and in macrophytes (seaweeds and seagrass) [64] was investigated from three different beaches on Gran Canaria Island (Spain). Analytical methods have already been described in Sections 2.1.1 and 2.1.2.…”

Section: Environmental and Biota Marine Matricesmentioning

confidence: 99%

The Application of Liquid Chromatography for the Analysis of Organic UV Filters in Environmental and Marine Biota Matrices

Nieddu,

Pasciu,

Demontis

et al. 2024

Separations

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Sunscreens are topical preparations containing one or more compounds that protect humans from ultraviolet (UV) light. This review focuses on analytical methods, particularly liquid chromatography, with the aim of identifying and determining UV filters (UVFs) in environmental and marine biota matrices. A literature review was conducted using NIH (PubMed and Medline), FDA and EPA databases, Google Scholar, and federal regulations. This retrospective literature review is focused on the last five years. UVF quantification in environmental and biological matrices showed a wide array of methods where liquid chromatography is predominant. The scientific literature identified a large variety of analytical methodologies that are compared in this review to evaluate the better results in terms of limits of quantification and the possibility to identify as many analytes as possible simultaneously.

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“…Existe uma grande preocupação, principalmente relacionada aos filtros químicos sobre seus efeitos potenciais em organismos aquáticos e possível atividade endócrina (Duis et al, 2022). A presença de filtros ultravioleta orgânicos sintéticos tem efeitos negativos na biota aquática devido seu acúmulo ou exposição a longo prazo, produzindo branqueamento de corais, prejudicando a reprodução, causando malformação e aumento da mortalidade para alguns organismos marinhos (Cadena-Aizaga et al, 2022). Deste modo, para lidar com estes problemas relacionados a sustentabilidade dos protetores solares, vem se procurando cada vez mais alternativas derivadas de fontes renováveis para esses aditivos químicos.…”

Section: Filtros Uvunclassified

Sustentabilidade no processo produtivo da indústria cosmética: uma revisão da literatura

Furman

Veit²,

Palácio³

et al. 2022

RSD

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A indústria cosmética é um setor que está sempre em crescimento, a nível mundial e nacional. Nos últimos tempos, o tema sustentabilidade neste setor tem recebido grande interesse dos consumidores, indústrias e organizações de cosméticos. Diante desta percepção, essa revisão sistemática de literatura objetiva explorar a relação entre a sustentabilidade e a indústria de cosméticos e, a possibilidade de substituir matérias-primas convencionais pelas de origem natural e sustentáveis. A coleta de dados foi realizada no período de novembro de 2021 a maio de 2022, nas bases eletrônicas: Scielo, Science Direct, Web of Science, Periódicos CAPES e Google Acadêmico. Para o processo industrial ser considerado sustentável, se destaca a necessidade de avaliar todas as fases do ciclo de vida do produto cosmético, de acordo com os aspectos ambientais, sociais e econômicos. Entretanto, a fase de seleção de matérias-primas é a mais desafiadora, pois deve-se levar em consideração a segurança e a função de cada ingrediente, a estabilidade da formulação, a vida útil do produto e a preferência do consumidor. Há também muitas definições e certificações que acabam deixando o tema confuso e disperso. Sendo assim, alcançar uma produção mais sustentável em relação aos produtos cosméticos é um processo contínuo, que visa muitas mudanças e inovações para desenvolver alternativas seguras e sustentáveis. A partir das informações coletadas com a presente revisão é esperado que as possibilidades de substituições de ingredientes nas formulações cosméticas inspirem maiores esforços colaborativos das comunidades cientificas e das indústrias do setor para se alcançar uma produção mais sustentável.

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Assessment of anthropogenic pollution by UV filters using macrophytes as bioindicators

Cited by 4 publications

References 24 publications

Salting-out assisted liquid–liquid extraction combined with LC–MS/MS for the simultaneous determination of seven organic UV filters in environmental water samples: method development and application

Salting-out assisted liquid–liquid extraction combined with LC–MS/MS for the simultaneous determination of seven organic UV filters in environmental water samples: method development and application

The Application of Liquid Chromatography for the Analysis of Organic UV Filters in Environmental and Marine Biota Matrices

Sustentabilidade no processo produtivo da indústria cosmética: uma revisão da literatura

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