Aspects of inhibition in electrodeposition of compact metals II. Effects of morphological interface inhibition

A comparative study of rhenium coatings prepared on graphite wafers by chemical vapor deposition and electrodeposition in molten salts

“…New steps can be reproduced by 2D nucleation [28]. Multiplying of these microsteps (which is called “bunching”) leads to the formation of macrosteps [29]. Besides, it has been confirmed by XRD result that most CVD Re crystals were oriented with the densely populated (002) plane parallel to the substrate.…”

A comparative study of rhenium coatings prepared on graphite wafers by chemical vapor deposition and electrodeposition in molten salts

“…New steps can be reproduced by 2D nucleation [28]. Multiplying of these microsteps (which is called “bunching”) leads to the formation of macrosteps [29]. Besides, it has been confirmed by XRD result that most CVD Re crystals were oriented with the densely populated (002) plane parallel to the substrate.…”

Effects of Organic Additives on Grain Growth in Electrodeposited Cu Thin Film during Self-Annealing

“…When a film is electrodeposited, the growth types of the grains vary with the deposition conditions. When the deposition rate is fast, grains exhibit various crystalline orientations, 23,[44][45][46] because the increase of the deposition rate suppresses the surface diffusion of the Cu ions, which is for finding energetically stable sites where they can be deposited. Therefore, the FWHM value of the rocking curve must increase.…”

“…This type of film deposit is called field-oriented texture type (FT type). 23,44,47 In these cases, the deposition current density is the only factor that affects the formation of the preferred orientation. However, the F PEG-SPS showed different tendency.…”

“…7b. 23,44,47 Therefore, a high stress is accumulated by the formation of a high-angle misorientation under the effect of both additives. This energy induced the drastic grain growth of the F PEG-SPS during the self-annealing.…”

Elucidation of the Structural Texture of Electrodeposited Ni/SiC Nanocomposite Coatings

“…A reasonable inhibiting species is adsorbed hydrogen, as it is generated as part of the electrochemical process. Another inhibiting specie is believed to be Ni­(OH) 2 , which is caused by a pH rise in the electrolyte when H + ions arriving at a nickel cathode are discharged and adsorbed. , Further, inorganic species such as SiC nanoparticles may be adsorbed on the cathode and are added to produce changes in morphology and to alter the texture axes of electrodeposits. , …”

A comparative study of rhenium coatings prepared on graphite wafers by chemical vapor deposition and electrodeposition in molten salts

“…New steps can be reproduced by 2D nucleation [28]. Multiplying of these microsteps (which is called “bunching”) leads to the formation of macrosteps [29]. Besides, it has been confirmed by XRD result that most CVD Re crystals were oriented with the densely populated (002) plane parallel to the substrate.…”

Effects of Organic Additives on Grain Growth in Electrodeposited Cu Thin Film during Self-Annealing

“…When a film is electrodeposited, the growth types of the grains vary with the deposition conditions. When the deposition rate is fast, grains exhibit various crystalline orientations, 23,[44][45][46] because the increase of the deposition rate suppresses the surface diffusion of the Cu ions, which is for finding energetically stable sites where they can be deposited. Therefore, the FWHM value of the rocking curve must increase.…”

“…This type of film deposit is called field-oriented texture type (FT type). 23,44,47 In these cases, the deposition current density is the only factor that affects the formation of the preferred orientation. However, the F PEG-SPS showed different tendency.…”

“…7b. 23,44,47 Therefore, a high stress is accumulated by the formation of a high-angle misorientation under the effect of both additives. This energy induced the drastic grain growth of the F PEG-SPS during the self-annealing.…”

Elucidation of the Structural Texture of Electrodeposited Ni/SiC Nanocomposite Coatings

“…A reasonable inhibiting species is adsorbed hydrogen, as it is generated as part of the electrochemical process. Another inhibiting specie is believed to be Ni­(OH) 2 , which is caused by a pH rise in the electrolyte when H + ions arriving at a nickel cathode are discharged and adsorbed. , Further, inorganic species such as SiC nanoparticles may be adsorbed on the cathode and are added to produce changes in morphology and to alter the texture axes of electrodeposits. , …”

A comparative study of rhenium coatings prepared on graphite wafers by chemical vapor deposition and electrodeposition in molten salts

“…New steps can be reproduced by 2D nucleation [28]. Multiplying of these microsteps (which is called “bunching”) leads to the formation of macrosteps [29]. Besides, it has been confirmed by XRD result that most CVD Re crystals were oriented with the densely populated (002) plane parallel to the substrate.…”

Effects of Organic Additives on Grain Growth in Electrodeposited Cu Thin Film during Self-Annealing

“…When a film is electrodeposited, the growth types of the grains vary with the deposition conditions. When the deposition rate is fast, grains exhibit various crystalline orientations, 23,[44][45][46] because the increase of the deposition rate suppresses the surface diffusion of the Cu ions, which is for finding energetically stable sites where they can be deposited. Therefore, the FWHM value of the rocking curve must increase.…”

“…This type of film deposit is called field-oriented texture type (FT type). 23,44,47 In these cases, the deposition current density is the only factor that affects the formation of the preferred orientation. However, the F PEG-SPS showed different tendency.…”

“…7b. 23,44,47 Therefore, a high stress is accumulated by the formation of a high-angle misorientation under the effect of both additives. This energy induced the drastic grain growth of the F PEG-SPS during the self-annealing.…”

Elucidation of the Structural Texture of Electrodeposited Ni/SiC Nanocomposite Coatings

“…A reasonable inhibiting species is adsorbed hydrogen, as it is generated as part of the electrochemical process. Another inhibiting specie is believed to be Ni­(OH) 2 , which is caused by a pH rise in the electrolyte when H + ions arriving at a nickel cathode are discharged and adsorbed. , Further, inorganic species such as SiC nanoparticles may be adsorbed on the cathode and are added to produce changes in morphology and to alter the texture axes of electrodeposits. , …”