Application of Seeded Membrane Distillation Crystallization for Zero Liquid Discharge

Abstract

Zero liquid discharge (ZLD) is a crucial requirement in industrial operations concerned with water scarcity and environmental protection. This study investigates the feasibility of using membrane distillation combined with crystallization (MDC) as a potential solution for ZLD. High‐saline NaCl solutions were used to evaluate the performance of a seeded MDC system, which demonstrated excellent recovery rates for both water (over 95 %) and salt (over 95.5 %). The presence of seeding crystals in the MDC system was found to inhibit membrane wetting. The MDC system achieved an average thermal efficiency of 61.5 %, showcasing its potential for long‐term processes. These results indicate that introducing seed crystals to the membrane's feed side enhances the MDC system's viability as a promising solution for ZLD. Additionally, the MDC system offers the prospect of high water and salt recovery, making it a sustainable approach to wastewater treatment and water reclamation.