In this article, the authors present methods based on hard coal that may ensure energy security for European Union countries. The research was carried out based on the example of Poland. The main reason for which coal is being gradually withdrawn from the energy mixes in EU countries is its negative impact on the natural environment and the health of citizens and economic factors related to domestic fuel production. The authors propose the creation of energy–chemical clusters as a solution to these problems. It is assumed that the clusters would operate following the principles of the circular economy. We also propose methods for the optimization of the production and transport costs within the cluster. Then, we conduct profitability analysis of the proposed waste management methods. At the level of the designated cluster, using network algorithms enabled us to reduce the transport costs by at least 50%. It is possible to obtain rare earth elements (REEs) worth USD 22,970 from 1 Mg of ash. At the level of the analyzed cluster, this leads to an annual profit of USD 3.5 billion. The profit related to algae production at the cluster level is approximately USD 2.5 bn.