Uniform geometrical theory of diffraction method is applied to the calculation of electromagnetic distribution and situation in urban environment in this article. Analytical hexahedrons are used as mathematical modeling of urban buildings and double diffractions between edges of buildings are mainly stated. Double diffractions between parallel edges are traced analytically while double diffractions between non-parallel edges are searched by numerical measures. Antennas are simulated by using the high-order moment method and a quasi-hybrid scheme is used to gain connection to UTD method. The accuracy of the proposed method is illustrated by compare of simulations and the engineering application value is shown by compare of actual measurements. The presented can realize the simulation analysis of electromagnetic distribution in large-scale urban environment on one common computer without extra computing resources.