An efficient factor for fast screening of high-performance two-dimensional metal–organic frameworks towards catalyzing the oxygen evolution reaction

Hai, Guangtong; Gao, Hongyi; Huang, Xiubing; Li, Tan; Xue, Xiangdong; Feng, Shihao; Wang, Ge

doi:10.1039/d2sc00377e

Cited by 14 publications

(8 citation statements)

References 44 publications

(75 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…These consequences shorten the diffusion lengths of the products and reactants to improve the performance of an electrocatalyst significantly. [ 101–105 ] As demonstrated by Liu et al, the ultrathin 2D Fe‐doped NiS/MoS 2 nanosheets exhibited significantly improved catalytic performance, attributed to the plenty of exposed active sites on ultrathin nanosheets. [ 104 ] Furthermore, various compositions in 2D MOF nanosheets, made of transition metal nodes, ligands substitution, and doping of extra atoms, [ 106 ] have provided an understanding of reaction mechanisms to achieve highly efficient electrocatalysts.…”

Section: D Mofs For Efficient Electrocatalystsmentioning

confidence: 99%

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis

et al. 2022

View full text Add to dashboard Cite

The 2D nanosheets of metal–organic frameworks (MOFs) have recently emerged as a promising material that makes them valuable in widespread electrocatalytic fields due to their atomic‐level thickness, abundant active sites, and large surface area. Efficient electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and overall water splitting are highly desired with low overpotentials to promote the industrial applications of energy conversion and devices. 2D MOF nanostructures provide long‐term stability and high electrical conductivity to enhance catalyst activity and durability. This review briefly summarizes the synthesis and electrocatalytic applications of 2D MOF for HER/OER/water splitting. More attention is focused on the synthetic strategies of 2D MOF and their derivatives. The catalytic performance and superior properties of these materials are highlighted. The outperformance of these materials originates from the rational design, myriad of abundant active sites, and atomic‐level thickness. The current and future challenges in this field and the scientific perspectives to overcome these challenges are highlighted. It is suggested that the construction of 2D MOF nanostructures can develop a state‐of‐the‐art electrocatalyst in energy and environmental division.

show abstract

Section: D Mofs For Efficient Electrocatalystsmentioning

confidence: 99%

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis

et al. 2022

View full text Add to dashboard Cite

show abstract

“…3–6 Despite extensive research efforts to accelerate anodic oxidation, substantial voltages are still necessary, considering the high theoretical equilibrium potential of 1.23 V for OER. 7–10…”

Section: Introductionmentioning

confidence: 99%

Length-tunable Pd₂Sn@Pt core–shell nanorods for enhanced ethanol electrooxidation with concurrent hydrogen production

Li¹,

Wang²,

Zhang³

et al. 2023

Chem. Sci.

View full text Add to dashboard Cite

show abstract

“…Metal–organic frameworks (MOFs) are a kind of porous materials constructed by coordination bonds between organic ligands and metal nodes. − Due to their large specific surface area, accessible active metal sites, and adjustable porosity, MOFs have become one of the most promising electrocatalytic materials and have attracted more and more attention. − In recent years, great efforts have been devoted to developing various efficient MOF-based electrocatalytic materials for CO 2 RR, including rational confinement engineering, MOF encapsulation, , ligand engineering, hydrophobic perfluoroalkane modification, and so on. Although these strategies have achieved great success, they are often limited by the tedious synthesis process. , In other words, it is of great significance to screen out MOF materials that can be directly used for electrocatalytic CO 2 RR without further processing.…”

Section: Introductionmentioning

confidence: 99%

High-Throughput Computational Screening of Metal–Organic Frameworks as High-Performance Electrocatalysts for CO₂RR

et al. 2022

Self Cite

View full text Add to dashboard Cite

Metal–organic frameworks (MOFs) are considered as promising electrocatalytic materials for the carbon dioxide reduction reaction (CO2RR) due to their various excellent properties. Here, through multistep high-throughput screening of the Computation-Ready, Experimental (CoRE) MOF database, including structural rationality check, pore size screening, adsorption capacity prediction, open metal site identification, CO2 molecular activation capacity, and reaction path calculation, MOFs named GAFRUD, CAJQEL, and cg400449c are identified as potential catalysts for electrocatalytic CO2RR. Furthermore, based on density functional theory calculations, we propose that the polarity of the coordination bonds between the metal atoms and the coordination atoms in ligands has a significant impact on the activation of CO2 molecules, and the selectivity of HCOOH mainly depends on the adsorption energy difference between *HCOO and *COOH. This principle is further validated by the experimental results, which will provide guidelines for the rational design of MOF-based electrocatalysts for CO2RR.

show abstract

An efficient factor for fast screening of high-performance two-dimensional metal–organic frameworks towards catalyzing the oxygen evolution reaction

Abstract: Two-dimensional (2D) Metal-Organic frameworks (MOFs) are promising materials for catalyzing oxygen evolution reaction (OER) due to abundant exposed active sites and high specific surface area. However, how to fast screen...

Cited by 14 publications

References 44 publications

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis

Length-tunable Pd₂Sn@Pt core–shell nanorods for enhanced ethanol electrooxidation with concurrent hydrogen production

High-Throughput Computational Screening of Metal–Organic Frameworks as High-Performance Electrocatalysts for CO₂RR

Contact Info

Product

Resources

About

An efficient factor for fast screening of high-performance two-dimensional metal–organic frameworks towards catalyzing the oxygen evolution reaction

Abstract: Two-dimensional (2D) Metal-Organic frameworks (MOFs) are promising materials for catalyzing oxygen evolution reaction (OER) due to abundant exposed active sites and high specific surface area. However, how to fast screen...

Cited by 14 publications

References 44 publications

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis

Current Progress in 2D Metal–Organic Frameworks for Electrocatalysis

Length-tunable Pd2Sn@Pt core–shell nanorods for enhanced ethanol electrooxidation with concurrent hydrogen production

High-Throughput Computational Screening of Metal–Organic Frameworks as High-Performance Electrocatalysts for CO2RR

Contact Info

Product

Resources

About

Length-tunable Pd₂Sn@Pt core–shell nanorods for enhanced ethanol electrooxidation with concurrent hydrogen production

High-Throughput Computational Screening of Metal–Organic Frameworks as High-Performance Electrocatalysts for CO₂RR