2017
DOI: 10.1039/c7gc00341b
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Abstract: Acrolein is the simplest unsaturated aldehyde, which – due to its high reactivity – has found application as an intermediate in the chemical industry.

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Cited by 13 publications
(14 citation statements)
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“…Besides the processes that have been reported and applied to the industrial production of acrolein, continuous research has been undertaken to further develop more environmentally friendly methods starting from renewable feedstocks and to optimize the cost of the production process …”
Section: Introductionmentioning
confidence: 99%
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“…Besides the processes that have been reported and applied to the industrial production of acrolein, continuous research has been undertaken to further develop more environmentally friendly methods starting from renewable feedstocks and to optimize the cost of the production process …”
Section: Introductionmentioning
confidence: 99%
“…In this respect, alcohol oxidative coupling of methanol and ethanol has been recently proposed and extensively studied as a potential method to replace the current fossil‐based production of acrolein from propylene . In this process, which takes place in the gas phase, acrolein can be directly synthesized in a single reactor, thus minimizing the investment costs …”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…Simultaneously, the product distributions of saturated aliphatic alcohols (C 3 and C 5 , C 4 and C 6 ) show an opposite trend ( Table 1). These findings reveal that high concentration of methanol possibly favors the formation of enal intermediates with odd carbon number, such as acrolein, [27] which then undergoes cross-condensation with 2-butenal and dehydrocyclization to BA=O/À OH, rather than hydrogenation to n-propanol. As shown in Table 1, approximately 60% carbon atoms in the consumption of CH 3 OH are incorporated into the aromatic alcohols.…”
Section: Resultsmentioning
confidence: 94%
“…Methanol is known as an abundant C1 platform molecule from syngas chemistry. [25,26] Cofeeding of methanol and ethanol was recently reported to form acrolein, [27] isobutanal, [28] and iso-butanol [29,30] over metal and/or acid-base catalysts. During these reactions, formaldehyde as a key intermediate for subsequent cascade reactions was confirmed as the primary product from methanol dehydrogenation and its cross-condensation with acetaldehyde yields acrolein.…”
Section: Introductionmentioning
confidence: 99%