Advanced functional materials in solid phase extraction for ICP-MS determination of trace elements and their species - A review

He, Man; Huang, Lijin; Zhao, Bingshan; Chen, Beibei; Hu, Bin

doi:10.1016/j.aca.2017.03.047

Cited by 153 publications

(42 citation statements)

References 184 publications

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“…Fewer review papers were published this year in comparison to previous years, perhaps reflecting the maturity of the methods currently used, and tended to be more specific-for example on the use 64 of functionalised nanomaterials for SPE prior to analysis by ICP-MS (190 references) or the continued use 65 of micro-extraction for speciation analysis of Se in various matrices including water (52 references). The endless quest to extract Cd from environmental matrices was extensively covered 66 (91 references).…”

Section: Sample Preconcentration and Extractionmentioning

confidence: 99%

Atomic Spectrometry Update – a review of advances in environmental analysis

Bacon

Butler

Cairns

et al. 2019

J. Anal. At. Spectrom.

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Section: Sample Preconcentration and Extractionmentioning

confidence: 99%

Atomic Spectrometry Update – a review of advances in environmental analysis

Bacon

Butler

Cairns

et al. 2019

J. Anal. At. Spectrom.

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“…Solid-phase extraction using a chelating resin is one of the useful techniques for separation and preconcentration of trace elements. [1][2][3][4] Chelating resins immobilizing various functional groups can be purchased from suppliers; 4 among them, a chelating resin immobilizing aminocarboxylic acid is widely used because it can extract many elements. 5 New generation of the chelating resins immobilizing aminocarboxylic For the carboxymethylation of amino group in PAA on the resin, 1 g of the resin immobilizing PAA was taken, and then 10 mL of 1 mol L -1 sodium hydroxide solution containing various amounts of MCA were added; the amounts are appended in Table 1.…”

Section: Introductionmentioning

confidence: 99%

Potential of Carboxymethylated Polyallylamine as a Functional Group on Chelating Resin for Solid-Phase Extraction of Trace Elements

et al. 2020

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New chelating resins immobilizing carboxymethylated polyallylamine (CM-PAA) were prepared by immobilizing PAAs with some molecular weights on methacrylate resins and then carboxymethylating a part of amino groups in the PAAs using various amounts of sodium monochloroacetate. The molecular weight of PAA barely affected both the amount of PAA immobilized on the resin and the relationship between the carboxymethylation (CM) rate and the ratio of the amount of monochloroacetate used in the CM step. The selectivity of CM-PAA resin for solid-phase extraction of trace elements was almost the same as that of a resin immobilizing carboxylymethylated polyethyleneimine; 10 elements, namely Cd, Co, Cu, Fe, Mo, Ni, Pb, Ti, V, and Zn, could be quantitatively recovered over a wide pH range and alkali and alkaline earth elements were scarcely extracted under acidic and neutral conditions. The CM-PAA resin was applicable to the separation and preconcentration of the elements in a certified reference material (Waste Water, EU-L-1) and a real environmental water sample (ground water). Keywords Chelating resin immobilizing carboxymethylated polyallylamine; solid-phase extraction; trace element; selectivity; environmental water sample acid, namely NOBIAS Chelate PA-1 (Hitachi High-Tech Fielding), 5-19 InertSep ME-2 (GL Science), 20 and Presep PolyChelate (FUJIFILM Wako Pure Chemical), 5,13,21-28 have been developed and the application of these resins for solid-phase extraction of trace elements in environmental samples has recently increased. These resins scarcely extract alkali and alkaline earth elements, which are sometimes contained at high concentration in various environmental samples and are often interfered with the determination of trace elements using atomic spectroscopy, under acidic and neutral conditions. 5,20 The selectivity of such chelating resins has been studied using chelating resins immobilizing Analytical Sciences

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Section: Introductionmentioning

confidence: 99%

“…Solid-phase extraction is widely utilized for separation and preconcentration of trace elements; [1][2][3][4] various solid-phase extraction materials, including chelating resin, are proposed even now. [1][2][3][4][5][6][7] A chelating resin immobilizing carboxymethylated polyethyleneimine (CM-PEI), which is commercially available as Presep PolyChelate (FUJIFILM Wako Pure Chemical), has an excellent ability for solid-phase extraction of trace elements. [8][9][10][11][12][13][14][15] This resin is prepared by immobilizing PEI on a porous methacrylate resin (copolymer of glycidyl methacrylate and ethylene glycol dimethacrylate) and then carboxymethylating amino groups in the PEI using sodium monochloroacetate.…”

Section: Introductionmentioning

confidence: 99%

Thermal Decomposition Behavior of a Chelating Resin Immobilizing Carboxymethylated Polyethyleneimine: Possibility of Estimation of Carboxymethylation Rate

et al. 2019

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Chelating resins immobilizing carboxymethylated polyethyleneimine (CM-PEI) with different carboxymethylation rates were prepared. The thermal decomposition behavior of CM-PEI resins was investigated using thermogravimetrydifferential thermal analysis/photo ionization-quadrupole mass spectrometry (TG-DTA/PI-QMS) and ion attachment ionization-quadrupole mass spectrometry equipped with direct inlet probe (DIP/IA-QMS). The obtained results suggested that the carboxymethyl group decomposed at relatively low temperature (150 C-300 C); the peak areas at m/z 45 and 59 in TG-DTA/PI-QMS and m/z 58, 70, and 72 in DIP/IA-QMS significantly increased with increasing carboxymethylation rate. These relationships should be useful for estimating the carboxymethylation rate of CM-PEI resin.

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Advanced functional materials in solid phase extraction for ICP-MS determination of trace elements and their species - A review

Cited by 153 publications

References 184 publications

Atomic Spectrometry Update – a review of advances in environmental analysis

Atomic Spectrometry Update – a review of advances in environmental analysis

Potential of Carboxymethylated Polyallylamine as a Functional Group on Chelating Resin for Solid-Phase Extraction of Trace Elements

Thermal Decomposition Behavior of a Chelating Resin Immobilizing Carboxymethylated Polyethyleneimine: Possibility of Estimation of Carboxymethylation Rate

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