A two-symmetric electrode hydride supercapacitor developed from G-C₃N₄ decorated with poly-2-aminobenzenethiol

Abstract

The incorporation of poly-2-aminobenzene thiol (P2ABT) onto 2D G-C3N4 sheets results in the formation of a P2ABT/G-C3N4 nanocomposite, exhibiting favorable morphological and electrical properties that position it as a promising candidate for a paste utilized in a two-symmetric electrode hydride supercapacitor. The decoration process involves the oxidation of 2-aminobenzene thiol with K2S2O8, leading to the polymer coating of the embedded 2D G-C3N4 materials, yielding a robust composite. Analysis via scanning electron microscopy (SEM) unveils the formation of 2D sheets of G-C3N4 with an average length, width, and thickness of 750 nm, 200 nm, and 15 nm, correspondingly. The composite establishes a sturdy network with a porous structure, indicative of the synergistic combination of the electrical characteristics of the polymer and G-C3N4.
In the construction of the two-symmetric electrode supercapacitor, an impressive specific capacitance (CS) of 310 F/g is achieved at 0.2 A/g. The supercapacitor exhibits a promising energy density (E) of 26.8 W h kg-1 and maintains retention stability even after undergoing 1000 charge/discharge cycles. Notably, the retention rate remains high at 98 % after 250 cycles and 96 % after an extended cycling period of 1000 cycles. This exceptional performance positions the supercapacitor as a prospective candidate for applications in industrial settings and within batteries. Its advantages lie in its ease of fabrication, mass production capabilities, and cost-effective manufacturing techniques, opening new avenues for these materials in energy storage fields.