2004
DOI: 10.1149/1.1819790
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A Safe, Low-Cost, and Sustainable Lithium-Ion Polymer Battery

Abstract: A polymer lithium-ion battery, formed by a Li 4/3 Ti 5/3 O 4 -LiFePO 4 electrode combination and a poly͑vinylidene fluoride͒ ͑PVdF͒based gel electrolyte, is presented and discussed. The electrochemical characterization demonstrates that this battery is capable of delivering appreciable capacity values at rates ranging from C/32 ͑160 mAh g Ϫ1 ͒ to 0.75C ͑130 mAh g Ϫ1 ͒, this being accompanied by a remarkable cycle life. In addition, because the two electrodes are based on common and nontoxic materials and opera… Show more

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Cited by 83 publications
(63 citation statements)
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“…[13,14] Based on these advantages, prototype lithium batteries have been constructed using nanoparticulate Li 4 Ti 5 O 12 in place of graphite ( Figure 3). [15] However, the capacity to store lithium is only half that of graphite, 150 mA h g À1 compared with 300 mA h g À1. This fact, combined with the reduced cell voltage because of the increased potential of the negative electrode, namely 0 to 1.5 V, leads to a reduced energy density.…”
Section: Nanotubes/wiresmentioning
confidence: 99%
“…[13,14] Based on these advantages, prototype lithium batteries have been constructed using nanoparticulate Li 4 Ti 5 O 12 in place of graphite ( Figure 3). [15] However, the capacity to store lithium is only half that of graphite, 150 mA h g À1 compared with 300 mA h g À1. This fact, combined with the reduced cell voltage because of the increased potential of the negative electrode, namely 0 to 1.5 V, leads to a reduced energy density.…”
Section: Nanotubes/wiresmentioning
confidence: 99%
“…It was originally proposed in 2003 by Ohzuku and co-workers 19 and in 2004 by us 20 , and it is presently exploited in various laboratories 21,22 . With this work, we have marked a step forward in the fi eld as the LTO / LNMO battery here reported shows rate, life and energy performance, to our knowledge, never reached before.…”
Section: Batterymentioning
confidence: 99%
“…carbon). [3] The inherent low cost, nontoxicity, and extremely high stability of LiFePO 4 has naturally led to intensive battery development toward large-scale applications, such as plug-in hybrid vehicles. [4] This material has intrinsically poor ionic and electronic conductivity.…”
mentioning
confidence: 99%