A Rapid and Efficient Access to Diaryldibenzo[b,f][1,5]diazocines

Quinolines Formation by Condensation of Heteroaromatic Ketones and 2‐Aminobenzophenones under MW Irradiation

“…Moreover, their reversible conformational changes during electrochemical redox processes make them interesting building blocks for molecular machines and artificial muscles . Conventional synthesis methods preparing dibenzo[b,f][1,5]diazocines required long reflux times, which in this paper was dramatically changed to solvent‐less, no‐heat‐required, and 3 min reaction.…”

Synthesis of 2‐Substituted Quinolines via Rhodium(III)‐Catalyzed C–H Activation of Imidamides and Coupling with Cyclopropanols

“…We recently reported the ortho homoenolation of arenes using cyclopropanols via ar hodium(III)-catalyzed C-H activation pathway. [14] To further realize cyclization of the b-aryl ketone intermediate,abifunctional nucleophilic directing group that attacks the resulting carbonyl group needst ob ee mployed.W en oted that amidines, [15] imidates, [16] benzamides, [17] andp henylhydrazine [18] bearing an NH group might serve this purpose.W en ow disclose ar hodium(III)-catalyzed annulative coupling between cyclopropanols and amidines for the synthesiso f2substituted quinolines.…”

Synthesis of novel polydiazocine for electroactive materials based on diazocine

“…21 Recently, we developed a new and efficient one-pot reaction for the synthesis of dibenzoen[b,f] [1,5] diazocine. 22 The mechanism of the diazocine synthesis is assumed to proceed by an unprecedented cyclization of the isocyanate with the neighboring acyl group, followed by an unprecedented dimerization, which has been strongly supported by experimental evidences in our previous work. 23 Here, we focus on the further applications of this reaction to prepare novel ladder-like heterocycles polymers, polydiazocines (Fig.…”