1984
DOI: 10.1080/00150198408240090
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A phenomenological gibbs function for BaTiO3 giving correct e field dependence of all ferroelectric phase changes

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Cited by 125 publications
(87 citation statements)
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“…(1) For ferroelectricity, Landau and Demonshire (LD) theory is the most popular and successful one. 4,[12][13][14] Unfortunately, more than five coefficients are introduced in LD theory for the free energy expression and give no physical significance [see Appendix B]. For example, with the appropriate values of the coefficients in LD theory obtained from the experimental data, the phase transitions (or the spontaneous polar directions) can be predicted by minimizing the free energy with respect to the polarization, but we have no idea of what is the driving force.…”
Section: Introductionmentioning
confidence: 99%
“…(1) For ferroelectricity, Landau and Demonshire (LD) theory is the most popular and successful one. 4,[12][13][14] Unfortunately, more than five coefficients are introduced in LD theory for the free energy expression and give no physical significance [see Appendix B]. For example, with the appropriate values of the coefficients in LD theory obtained from the experimental data, the phase transitions (or the spontaneous polar directions) can be predicted by minimizing the free energy with respect to the polarization, but we have no idea of what is the driving force.…”
Section: Introductionmentioning
confidence: 99%
“…For example, the Landau polynomial as originally applied to ferroelectric barium titanate by Devonshire 188,189 has been elaborated on many times, and several alternative expressions for the free energy have been reported that reproduce experimental data with varying degrees of agreement. [190][191][192][193][194] The situation for ferroelectric solid solutions is more complicated still, because the dependence of the theory parameters on composition must also be explicitly determined. 195,196 Approaches for doing so that utilize analytical parameterization schemes have recently been reported.…”
Section: Challenges For Modeling Of Complex Oxide Heterostructuresmentioning
confidence: 99%
“…Подставим числа (9) в качестве значений ангармонических констант γ i и δ j в формулы (5), (6). В результате получим …”
Section: ландау-девоншира для титаната барияunclassified
“…Это значит, что существует механизм, уменьшающий величину δB (1) 2 и тем самым способствующий малости этой поправки по сравнению с δB (1) 1 . Не исключено, что с действием именно этого механизма связано отсутствие темпе-ратурной зависимости коэффициента B 2 , восстановленного по экспериментальным данным в работах [4], [6], [7], при том что зависимость от температуры B 1 выявлена в этих работах весьма отчетливо.…”
unclassified