A macrocyclic Pd(II)–Ni(II) complex in Heck and Suzuki reactions

Mieczyńska, Ewa; Lisowski, Jerzy; Trzeciak, Anna M.

doi:10.1016/j.ica.2014.11.008

Cited by 6 publications

(2 citation statements)

References 40 publications

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“…In 2015, Mieczynska and co‐workers reported a heterodinuclear Pd(II)–Ni(II) macrocyclic Schiff base complex ( C43 ) (Fig. ) and applied as a catalyst for the Suzuki and the Heck cross‐coupling reactions of 4‐bromoanisole with phenylboronic acid and styrene, respectively, affording the coupled products with yields up to 87–96%.…”

Section: Schiff Base Ligands and Their Metal Complexesmentioning

confidence: 99%

Recent Advances in the Schiff Bases and N‐Heterocyclic Carbenes as Ligands in the Cross‐Coupling Reactions: A Comprehensive Review

Kumar

2019

Journal of Heterocyclic Chem

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Cross‐coupling reactions, namely, the Suzuki–Miyaura, Heck, Sonogashira, Hiyama, Negishi, Kumada, and Hartwig–Buchwald, are the most powerful approaches in the formation of C–C, C–N, C–O, and C–S bonds for the complex organic scaffolds in drugs, natural products, organic materials, and fine chemicals. The nitrogen‐based ligands have upper hands in these reactions because they are air stable, inexpensive, and easier to handle than the phosphorous counterparts. In this perspective, Schiff bases and N‐heterocyclic carbenes have been explored extensively in terms of novel design and preparation as ligands in the coupling reactions. Facile recovery and reusability of these ligands make them eco‐friendly and economical. A comprehensive outline on the progress in Schiff bases–metal complexes and NHC–metal complexes that mediated cross‐coupling reactions with recent examples highlighted is reported (160 references).

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Section: Schiff Base Ligands and Their Metal Complexesmentioning

confidence: 99%

Recent Advances in the Schiff Bases and N‐Heterocyclic Carbenes as Ligands in the Cross‐Coupling Reactions: A Comprehensive Review

Kumar

2019

Journal of Heterocyclic Chem

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“…The products obtained in these reactions have been taken into account for their high prevalence in a wide variety of fields, including industrial, for the pharmaceutical, polymer, liquid crystals, agricultural chemical industries [14][15][16]. They are also used as natural products, molecular organic materials and components for optical device production [17,18]. Until now, soluble palladium(II) complexes with various ligands such as oxazolines, thioureas, pyridines, pyrazoles [19], imidazole [20], Schiff bases [21,22] and Nheterocyclic carbines [23] have been used as effective catalysts.…”

Section: Introductionmentioning

confidence: 99%

Schiff Base and Its Fe(II), Zn(II), Ru(II), Pd(II) Complexes Containing ONS Donor Atoms: Synthesis, characterization and Catalytic Studies

Buldurun¹,

Çolak²,

Özdemır³

et al. 2019

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The work include the synthesis, spectroscopic characterization and as well as catalytic activities of Fe(II), Zn(II), Ru(II), and Pd(II) complexes with a novel Schiff base ligand derived from methyl 2amino-5,5,7,7-tetramethyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate and salicylaldehyde. Spectroscopic techniques including IR, UV-Vis, NMR, and mass analysis as well as elemental analysis and magnetic susceptibility measurement were used to identify the compounds. Based on elemental and spectral studies octahedral geometry was proposed to Fe(II), Zn(II) and Ru(II) complexes and square planar geometry was proposed to Pd(II) complex. To improve more efficient and stable catalysts, we wanted to study if there is any influence the catalytic activity of ruthenium complex for the transfer hydrogenation of ketones and we wanted to examine the catalytic activities of palladium complex in Suzuki C-C cross coupling reactions under various conditions.

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Controllable preparation of one-dimensional hybrid catalytic materials of nickel nanoparticles/porous carbon fibers and study of their performance as catalyst for Heck reaction

Zhu

Bai

et al. 2016

J Porous Mater

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A macrocyclic Pd(II)–Ni(II) complex in Heck and Suzuki reactions

Cited by 6 publications

References 40 publications

Recent Advances in the Schiff Bases and N‐Heterocyclic Carbenes as Ligands in the Cross‐Coupling Reactions: A Comprehensive Review

Recent Advances in the Schiff Bases and N‐Heterocyclic Carbenes as Ligands in the Cross‐Coupling Reactions: A Comprehensive Review

Schiff Base and Its Fe(II), Zn(II), Ru(II), Pd(II) Complexes Containing ONS Donor Atoms: Synthesis, characterization and Catalytic Studies

Controllable preparation of one-dimensional hybrid catalytic materials of nickel nanoparticles/porous carbon fibers and study of their performance as catalyst for Heck reaction

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