In many real-time networks such as computer networks, each arc has stochastic capacity, lead time, and accuracy rate. Such a network is named a multi-state computer network (MSCN). Under the strict assumption that the capacity of each arc is deterministic, the quickest path (QP) problem is to find a path that sends a specific amount of data with minimum transmission time. From the viewpoint of internet quality, the transmission accuracy rate is one of critical performance indicators to assess internet network for system administrators and customers. Under both assured accuracy rate and time constraint, this paper extends the QP problem to discuss the flow assignment for a MSCN. An efficient algorithm is proposed to find the minimal capacity vector meeting such requirements. The system reliability, the probability to send d units of data through multiple minimal paths under both assured accuracy rate and time constraint, can subsequently be computed. Furthermore, two routing schemes with spare minimal paths are adopted to reinforce the system reliability. The enhanced system reliability according to the routing scheme is calculated as well. The computational complexity in both the worst case and average case are analyzed.