Abstract:We report the synthesis and characterization of a novel 4-(dimethylamino)pyridinium-substituted η-cycloheptatrienide-Pd complex which is free of halide ligands. Diacetonitrile{η-[4-(dimethylamino)pyridinium-1-yl]cycloheptatrienido}palladium(II) bis(tetrafluoroborate), [Pd(CHN)(CHN)](BF), was prepared by the exchange of two bromide ligands for noncoordinating anions, which results in the empty coordination sites being occupied by acetonitrile ligands. As described previously, exchange of only one bromide leads … Show more
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