Although
hydrogel-based electronic devices have received a lot
of interest for good flexibility, biocompatibility, and multifunctionality
over the past decades, underwater instability (especially in saline
solutions) still limits their practical applications to a wide range.
Herein, a class of tough, conductive, and anti-swelling double-network
hydrogel is developed by combining the zwitterionic poly(acrylamide-co-(3-(1-(4-vinylbenzyl)-1H-benzo[d]imidazole-3-ium-3-yl) propane-1-sulfonate)) chemical network
and water-resistant polyvinyl alcohol physical network with conducting
polypyrrole. The resultant gel exhibits considerable mechanical strength
(0.65 MPa), stable swelling dynamics in water and seawater, as well
as excellent ionic conductivity (3.96 S/m). Furthermore, the assembled
gel-based sensor shows distinct strain/temperature bi-modal detection.
Moreover, by controlling the dimension of conductive networks, an
all-in-one supercapacitor can be obtained, with ultra-high capacitance
(299.79 mF/cm2) and power density (2.49 mW/cm2). We believe that this strategy will inspire researchers to develop
more reliable underwater, self-powered multi-modal sensing devices
in the future.