In this study, FeSO
4
·7H
2
O was used as
an auxiliary depressant to improve the selective depression effect
on fluorite. Microflotation tests using oleic acid as the collector
showed that the pre-addition of FeSO
4
·7H
2
O and subsequent addition of sodium silicate (SS) resulted in a stronger
selective depression effect on fluorite compared with SS alone. Addition
of FeSO
4
·7H
2
O reduced the required dosage
of SS and had little negative effects on scheelite recovery. The selective
depression mechanism of FeSO
4
·7H
2
O was
investigated in detail. X-ray photoelectron spectroscopy indicated
that the difference in the number of surface active sites was the
mechanism for improved differential flotation of scheelite from fluorite.
The improved depression of fluorite was attributed to both ferrous
and sulphate ions. The pre-adsorption of ferrous species increased
the number of active sites, enhancing the adsorption of silicate species
on the fluorite surface. Simultaneously, sulfate ions were selectively
adsorbed on the fluorite surface to form hydrophilic calcium sulfate,
reducing the floatability of fluorite.