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Cited by 105 publications
(102 citation statements)
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References 66 publications
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“…On the other hand, the ratio between the H peak and plateau levels for n-decane is 3.9, thus similar to the one of n-propylcyclohexane (4.3, as mentioned above). This result, when compared to the work by Hong et al (2011), may suggest modifications in the kinetic model aimed at reducing the H-scavenging effects predicted for n-decane. These corrections would also benefit the simulation results of the n-decane profiles in Figure 1, since it would lead to shorter ignition delay times and to a reduction in the difference between the modeling and the experimental results.…”
Section: Supplementary Kinetic Considerationsmentioning
confidence: 70%
See 1 more Smart Citation
“…On the other hand, the ratio between the H peak and plateau levels for n-decane is 3.9, thus similar to the one of n-propylcyclohexane (4.3, as mentioned above). This result, when compared to the work by Hong et al (2011), may suggest modifications in the kinetic model aimed at reducing the H-scavenging effects predicted for n-decane. These corrections would also benefit the simulation results of the n-decane profiles in Figure 1, since it would lead to shorter ignition delay times and to a reduction in the difference between the modeling and the experimental results.…”
Section: Supplementary Kinetic Considerationsmentioning
confidence: 70%
“…The modeling results indicate that, at the conditions in Figure 9, the ratio between the maximum initial H peak and the plateau level is around a factor of 4.3, which is lower than the corresponding Downloaded by [University of Connecticut] at 08:45 01 April 2015 factor for n-butylbenzene (11.9) but still considerably high. In a previous study, Hong et al (2011) experimentally measured the OH profile for a (n-butylcyclohexane + O 2 ) mixture in 99.55% argon at a temperature of 1450 K and a pressure of 2.2 atm. The authors observed a strong scavenging effect, which was not present in the n-heptane profile measured by the authors at similar conditions.…”
Section: Supplementary Kinetic Considerationsmentioning
confidence: 99%
“…The formation of H 2 O is fast and steady starting from time zero, followed by a nearly constant H 2 O concentration. As suggested by Hong et al [31], this nearly constant H 2 O plateau level (after ignition) is predominantly controlled by relatively well-established thermodynamic parameters. This observation was also validated through the perturbation of the rate constants for the above important reactions, following which the final H 2 O concentration level effectively remained the same.…”
Section: -Pentanone Oxidationmentioning
confidence: 95%
“…The H 2 O profiles for typical hydrocarbons [18,19,31] exhibit sequential features: an initial gradual formation of H 2 O is followed by a rapid increase indicating ignition, which is in turn succeeded by a very slow rise in H 2 O concentration. During 3-pentanone oxidation, the H 2 O profiles are slightly different from those of common hydrocarbons (n-alkanes and cycloalkanes).…”
Section: -Pentanone Oxidationmentioning
confidence: 97%
“…The latter is a chain initiation reaction but is of less significance to CP dissociation than H abstraction. Hong et al 26 claimed that nearly 100% of H radical is recovered after H abstraction. The seldom methyl radical produced are responsible to turn the chain termination reactions, i.e., H abstraction, to chain propagation reactions, enhancing the reactivity during CH oxidation.…”
Section: Flux and Sensitivity Analysismentioning
confidence: 99%