As
one of the major short chain hydrocarbons resulting from the
cracking process, ethylene is often used as a surrogate for cracked
kerosene. In this study, a skeletal mechanism of ethylene was developed
under the typical working conditions of scramjet combustors. The skeletal
mechanism was reduced from a fully verified detailed mechanism under
the desired working conditions. An integrated reducing method containing
directed relation graph with error propagation method (DRGEP), sensitivity
analysis (SA), and computational singular perturbation (CSP) was employed
to obtain three skeletal mechanisms. A three-level fidelity validation
of the skeletal mechanisms respectively comparing the kinetic properties,
the global combustor performance, and the detailed flame structure
was proposed to comprehensively evaluate the skeletal mechanisms.
In the first-level fidelity validation, the three skeletal mechanisms
all show good agreement with the detailed one in the autoignition
delay and laminar flame speed over a wide range of working conditions.
Then in the second-level fidelity validation, the smallest mechanism
consisting of 24 species and 86 reactions (24S/86R) was further validated
through incorporating with the large eddy simulation of a realistic
scramjet combustor. Comparisons with the experimental data and the
predictions by the detailed mechanism show that the global combustor
performance (e.g., pressure, Mach number, and combustion efficiency)
was accurately predicted by the 24S/86R mechanism. In the third-level
fidelity evaluation, the flame structure characterized by the distribution
of CO, OH, and heat release rate was analyzed through comparing the
predictions by the 24S/86R mechanism with those by the detailed one
during which the insufficiency of the skeletal mechanism was also
recognized.