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Cited by 31 publications
(6 citation statements)
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“…The triphenylcarbenium ion formation is characterized by a double-peaked absorption band in the nm region of the spectrum [356]. Extinction coefficients of these bands are of the order of magnitude of l(f liter mol-1 cm -1, which permits a sensitive detection of the amounts of carbenium ions formed.…”
Section: Optical Spectroscopiesmentioning
confidence: 99%
See 1 more Smart Citation
“…The triphenylcarbenium ion formation is characterized by a double-peaked absorption band in the nm region of the spectrum [356]. Extinction coefficients of these bands are of the order of magnitude of l(f liter mol-1 cm -1, which permits a sensitive detection of the amounts of carbenium ions formed.…”
Section: Optical Spectroscopiesmentioning
confidence: 99%
“…Extinction coefficients of these bands are of the order of magnitude of l(f liter mol-1 cm -1, which permits a sensitive detection of the amounts of carbenium ions formed. However, the use of these molecules for the titration of acid sites on surfaces appears to be complicated by side reactions and by the fact that the carbenium ion formation is photocatalyzed [356].…”
Section: Optical Spectroscopiesmentioning
confidence: 99%
“…The hyperfine interaction between the electron and nuclear spin is represented by the second term of eq 1. The second rank tensor T that describes this interaction can be resolved into isotropic and anisotropic components. The effective Hamiltonian for the hyperfine interaction is then given by 3Chfs = AS-I + S-B-I (2) and the isotropic and anisotropic components of T correlate with the first and second terms, respectively, of eq 2. In eq 2 the first term is the Fermi or contact interaction and arises from the overlap of the nuclear and unpaired electron wave functions. This term was introduced by Fermi in the treatment of atomic hyperfine interaction, and he showed that the constant A is related to the value of the normalized wave function of the unpaired electron at the nucleus…”
Section: The Journal Of Physical Chemistrymentioning
confidence: 99%
“…(1) The outer four lines are parallel hyperfine, and the central line is the remaining parallel feature on which all the perpendicular components are overlapping. (2) The outer four lines are perpendicular features, and the central line is formed by overlap of the remaining perpendicular features and all the five parallel components. (3) Each line is formed by the overlap of a parallel and perpendicular feature.…”
Section: The Journal Of Physical Chemistrymentioning
confidence: 99%
“…The adsorption of electron acceptors on metal oxides has been investigated to study and characterize the electronic properties of metal oxides [1][2][3]. Two possible electron sources exist on the metal oxide responsible for the electron transfer.…”
mentioning
confidence: 99%