In this paper, we study divisorial ideals of a Hibi ring which is a toric ring arising from a partially ordered set. We especially characterize the special class of divisorial ideals called conic using the associated partially ordered set. Using our observation of conic divisorial ideals, we also construct a module giving a non-commutative crepant resolution (= NCCR) of the Segre product of polynomial rings. Furthermore, applying the operation called mutation, we give other modules giving NCCRs of it.Since conic divisorial ideals are related with the structure of the Frobenius push-forward of toric rings, we discuss them from a viewpoint of positive characteristic commutative algebra in Appendix.