Since the colloidal quantum dots (QDs) started being utilized as novel fluorescent materials in early 1980s, [1][2][3] great efforts and rapid progresses have been made during the last 30 years in QD-based solid-state lighting and flat-panel display technologies. [4][5][6][7] A principal character of QDs is the quantum confinement induced tunability of their emission color (from
The balance injection of holes and electrons into a thin emissive quantum dot (QD) layer for efficient radiative recombination is critical to the color purity, stability, and efficiency of the QD-based light-emitting diodes (QD-LEDs).Due to the difficulty of charge injection into wide band gap blue QD layer, the performance of blue QD-LED is obviously inferior to the green and red counterparts. Here, high-performance ZnCdS/ZnS graded core/shell-based blue QD-LEDs with partial oxidized aluminum cathode (Al:Al 2 O 3 ) via simple autoxidation are demonstrated. There is no any additional electron transport layer/hole transport layer involved in the device, which guarantees the color purity and simplifies the fabrication processes. Furthermore, the Al:Al 2 O 3 cathode greatly enhances the charge injection and exciton recombination, rendering significant improvement in luminance and current efficiency compared with the control devices with Al or Alq3/Al electrodes. A record luminance of over 13 000 cd m −2 has been achieved for blue QD-LEDs with Al:Al 2 O 3 cathode. The findings of this study indicate that this simply processed and easily controlled autoxidation procedure is a promising strategy to achieve high-performance blue QD-LEDs.