2017
DOI: 10.5155/eurjchem.8.3.218-223.1578
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Abstract: A new series of organotellurium compounds based on quinoline were prepared by the reaction of 8-(quinolyl)mercuric chloride (1) with tellurium tetrabromide in 1:1 and 1:2 mole ratio in dry dioxane to obtain 8-(quinolyl)tellurium tribromide (2) and bis [8-(quinolyl)]tellurium dibromide (3), respectively, in good yields. Reaction of compounds 2 and 3 by ethanolic hydrazine hydrate gave bis [8-(quinolyl)]ditelluride (4) and bis [8-(quinolyl)]telluride (5), respectively, in moderate yields. Furthermore, the ligand… Show more

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Cited by 5 publications
(7 citation statements)
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“…The molar conductance of complexes 1-8 were found at range 5.00-8.50 ohm -1 .cm 2 .mol -1 . This indicates that these complexes behave as non-electrolytes which are in agree well with previous literatures [26].…”
Section: Resultssupporting
confidence: 93%
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“…The molar conductance of complexes 1-8 were found at range 5.00-8.50 ohm -1 .cm 2 .mol -1 . This indicates that these complexes behave as non-electrolytes which are in agree well with previous literatures [26].…”
Section: Resultssupporting
confidence: 93%
“…The IR spectra of all new synthesized complexes 1-8 display common feature in certain region and characteristic bands in the fingerprint and other regions. The IR spectra of complexes 1, 2, 3, 5 and 7 show a broad band at 3333-3390 cm -1 range which attributed to N-H stretching [27,28]. The shift was observed toward low frequency for amino groups than the free ligands [21] at range 8-58 cm -1 due to the coordination of the palladium(II) ion with the amino groups.…”
Section: Resultsmentioning
confidence: 99%
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