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Cited by 7 publications
(16 citation statements)
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References 47 publications
(30 reference statements)
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“…A comparison of the spectra (Figures S4, S8, S12, S16, S22, S26, S30, S36 and S40) reveal that drastic changes in the chemical shifts could only be detected for the C(3) carbon atom, which is directly connected to the negatively charged oxygen atom. Therefore, this signal exhibited shifting toward lower values (shielding) from 1 ppm for oleylmethylbis(2-hydroxyethyl)ammonium ascorbate (10) to even 10 ppm for alkyltrimethylammonium ascorbates (1−3) in all the ILs analyzed. The phenomenon observed may be attributed to the alterations in the electron distribution within the ring of the ascorbate anion caused by the differences in the structures of the alkyl substituents of the cations utilized (see the optimized structures presented in the Supporting Information in Table S13).…”
Section: Acs Sustainable Chemistry and Engineeringmentioning
confidence: 96%
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“…A comparison of the spectra (Figures S4, S8, S12, S16, S22, S26, S30, S36 and S40) reveal that drastic changes in the chemical shifts could only be detected for the C(3) carbon atom, which is directly connected to the negatively charged oxygen atom. Therefore, this signal exhibited shifting toward lower values (shielding) from 1 ppm for oleylmethylbis(2-hydroxyethyl)ammonium ascorbate (10) to even 10 ppm for alkyltrimethylammonium ascorbates (1−3) in all the ILs analyzed. The phenomenon observed may be attributed to the alterations in the electron distribution within the ring of the ascorbate anion caused by the differences in the structures of the alkyl substituents of the cations utilized (see the optimized structures presented in the Supporting Information in Table S13).…”
Section: Acs Sustainable Chemistry and Engineeringmentioning
confidence: 96%
“…The new products included salts containing a cation substituted with one long alkyl chain trimethyltetradecylammonium (1), hexadecyltrimethylammonium (2), trimethyloctadecylammonium (3), and behenyltrimethylammonium (4); substituted with two long alkyl chains dimethyldioctylammonium (5), didecyldimethylammonium (6), dicocodimethylammonium (7), and di(hydrogenated tallow)dimethylammonium (8); substituted with one long alkyl chain along with a benzyl group benzalkonium (9); and substituted with one long alkyl chain along with two hydroxyethyl groups oleylmethylbis(2-hydroxyethyl)ammonium (10). It is notable that the cations of salts 7, 8, and 10 contain substituents derived from natural feedstocks: coco (from coconut oil), hydrogenated tallow (from animal tallow), and oleyl (from olive oil), which are defined in Table 2.…”
Section: Acs Sustainable Chemistry and Engineeringmentioning
confidence: 99%
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“…25 Deterrent ILs with a pelargonate anion have also been reported. 26 1,4-Diazabicyclo[2.2.2]octane (common name DABCO) is a bicyclic compound that belongs to the group of tertiary diamines. It is widely used as a catalyst for many reactions, both in pristine and modied forms.…”
Section: Introductionmentioning
confidence: 99%