Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)

Gümüş, İlkay; Solmaz, Ummuhan; Çelik, Ömer; Binzet, Gün; Balcı, Gülten Kavak; Arslan, Hakan

doi:10.5155/eurjchem.6.3.237-241.1265

Cited by 13 publications

(6 citation statements)

References 46 publications

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“…SHBH has good coordination ability for the studied metal ions. Its spectrum showed bands at 3282, 3163, 1644 and 1589 cm -1 due to (OH), (NH), (C=O) and (C=N), respectively [16]. The calculated energetic parameters shown in Table 8 for [Co3(SHBH-6H)(H2O)6] ( Figure 5) indicate exoergic process for the complex formation.…”

Section: Ir and Nmr Spectra Of Shbh And Complexesmentioning

confidence: 93%

Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide

2016

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Section: Ir and Nmr Spectra Of Shbh And Complexesmentioning

confidence: 93%

Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide

2016

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“…HL 1 and HL 2 were synthesized according to the procedures given in the literature. [55][56][57][58] All new palladium(II) complexes are air stable and soluble in common organic solvent such as acetone, dichloromethane, chloroform, 1,4-dioxane, dimethyl sulfoxide, and dimethylformamide (DMF), but insoluble in n-hexane, ethanol, and water.…”

Section: Synthesis Of Palladium(ii) Complexesmentioning

confidence: 99%

“…4-Chloro-N-(di-nethylcarbamothioyl)benzamide (HL 1 ) and 4-chloro-N-(din-propylcarbamothioyl)benzamide (HL 2 ) were prepared according to previously published method. [55][56][57][58] A solution of 4-chlorobenzoyl chloride (5 Â 10 À2 mol) in acetone (50 mL) was added dropwise to a suspension of potassium thiocyanate (5 Â 10 À2 mol) in acetone (30 mL). The reaction mixture was heated under reflux for 30 min and then cooled to room temperature.…”

Section: Synthesis Of Ligandsmentioning

confidence: 99%

Palladium complexes derived from benzoylthiourea ligands: Synthesis, crystal structure, and catalytic application in Suzuki C–C coupling reactions

Solmaz

Gümüş

Yılmaz

et al. 2021

Applied Organom Chemis

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PdCl 2 (HL 1 -κS) 2 ] and [PdCl 2 (HL 2 -κS) 2 ] complexes were formed from neutral monodentate modes of HL 1 and HL 2 ligands, which are coordinated to the palladium(II) center, respectively. [Pd(L 1 -κ 2 S,O) 2 ] and [Pd(L 2 -κ 2 S,O) 2 ] complexes were obtained by recrystallization of corresponding [PdCl 2 (HL 1 -κS) 2 ] and [PdCl 2 (HL 2 -κS) 2 ] complexes as anionic bidentate coordination modes. All palladium(II) complexes were characterized by elemental analysis, FT-IR, and

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“…HL 1,2 ligands were prepared according to previously published methods [38][39][40]. A solution of substituted benzoyl chloride (4-fluorobenzoyl chloride and 4-bromobenzoyl chloride, 5 mmol) in dry acetone (50 mL) was added dropwise to a suspension of potassium thiocyanate (5 mmol, 0.490 g) in acetone (30 mL).…”

Section: General Procedures For the Synthesis Of Ligands (Hl 12 )mentioning

confidence: 99%

Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands

et al. 2018

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Thiourea derivatives [N-(di-n-propylcarbamothioyl)-4-fluorobenzamide (HL1) and N-(di-n-propylcarbamothioyl)-4-bromobenzamide (HL2)] and their platinum complexes have been successfully synthesized and structurally characterized by spectroscopic 1H NMR, 13C NMR, COSY, HMQC, and FT-IR techniques. The structure of both complexes was also confirmed by single crystal X-ray diffraction studies. The study of X-ray single crystal diffraction shows that the supramolecular aggregation of the complexes is stabilized via weak interactions as well as stacking interactions such as C-H···π and π···π. The cis-[Pt(L1-S,O)2 showed C–H···π and π···π stacking interactions, whereas only C–H···π stacking interaction was observed in cis-[Pt(L2-S,O)2]. In addition, the strong classical and non-classical intermolecular hydrogen bonds are not found in the prepared complexes. Therefore, it can be said that the C–H···π and π···π stacking interactions play an important role in the formation of supramolecular structures of the complexes.

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Synthesis, characterization and crystal structure of cis-bis[4-fluoro-N-(diethylcarbamothioyl)benzamido-κ2O,S]platinum(II)

Cited by 13 publications

References 46 publications

Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide

Synthesis and characterization of tri- and tetra-metallic complexes of N'1,N'4-bis((E)-3,4-dihydroxybenzylidene)-succinohydrazide

Palladium complexes derived from benzoylthiourea ligands: Synthesis, crystal structure, and catalytic application in Suzuki C–C coupling reactions

Synthesis, characterization and crystal structure of platinum(II) complexes with thiourea derivative ligands

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