Abstract:The kinetics of oxidation of butylamine and isobutylamine by diperodatocuprate(III) (DPC) in alkaline medium has been studied spectrophotometrically in the temperatures range of . All data follow pseudo-first order reaction in [DPC] under experimental conditions. It was found that the reaction showed pseudo-first order with respect to DPC and 1 < nap < 2 to reductant. The rate constant kobs increased with increase in [reductant], however, the kobs decreased with increase in [IO4 -] and [OH -]. In addition, th… Show more
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