Mononuclear copper(I) complexes [CuL2]I (1), [CuL2]2[Cu2I4]·2MeCN (2) and [CuL2]PF6 (3) with a new chelating pyrazolylpyrimidine ligand, 2-(3,5-dimethyl-1H-pyrazol-1-yl)-4,6-diphenylpyrimidine (L), were synthesized. In the structures of complex cations [CuL2]+, Cu+ ions coordinate...