Detailed Evaluation of Pervaporation Modeling to Obtaining Anhydrous Ethanol

Abstract

Pervaporation requires operation at mild temperatures and provides low energy consumption, which makes this technology economically attractive. However, pervaporation is not yet a widespread process in the industry. One of the justifications is the complexity in the quantification of variables related to the membrane in the most diverse conditions. This factor results in the absence of generic models in the simulation software. This work aims at the rigorous phenomenological modeling of a pervaporation process using a polyetherimide membrane intended for the dehydration of ethanol. The model was developed on the Aspen Custom Modeler™ platform. Two approaches were implemented and compared: PERKAT and PERVAP models, being the last one the best model. The main variables of the process were evaluated. It was possible to verify the capacity of separation of the pervaporation module in breaking the barriers of the azeotrope, reaching a product with a high level of purity in ethanol, and recovery of up to 99.8%. In addition, the generic PERVAP model was exported to Aspen Plus™ and a cascade pervaporation unit was simulated. The specific energy consumption was calculated and compared to that of traditional separation processes. A 70% reduction was obtained compared to the most economical distillation configuration.

Design of a Gas Permeation and Pervaporation Membrane Model for an Open Source Process Simulation Tool

“…Cavalcanti et al, described a pervaporation membrane model based on the SDM integrated with the Aspen Custom Modeler. It was applied to predict the purification of EtOH with a polyetherimide membrane [30]. A high-pressure hollow fiber membrane contactor for natural gas purification was modeled for the PS tool gPROMS in a counter-current flow configuration [31].…”