2004
DOI: 10.1590/s0103-50532004000300002
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Abstract: Sais derivados do cátion 1,3-dialquilimidazólio são uma das mais populares e investigadas classes de líquidos iônicos a temperatura ambiente. Embora, em vários casos, suas propriedades físico-químicas e/ou o resultado dos processos que ocorrem nesses líquidos diferem significantemente daqueles obtidos em solventes orgânicos dipolares, estes ainda podem ser descritos como simples solventes orgânicos. Nesta revisão, será introduzido o conceito que líquidos iônicos derivados do cátion 1,3-dialquilimidazólio são m… Show more

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Cited by 812 publications
(695 citation statements)
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“…Full names MMIBF 4 1,3-Dimethylimdazolium tetrafluoroborate BMIBF 4 1-Butyl-3-methylimdazolium tetrafluoroborate HMIBF 4 1-Hexyl-3-methylimdazolium tetrafluoroborate BMMIBF 4 1-Butyl-2,3-dimethylimdazolium tetrafluoroborate HOMIBF 4 1-(2'-Hydroxylethyl)-3-methylimdazolium tetrafluoroborate BMIPF 6 1-Butyl-3-methylimdazolium hexafluorophosphate BMINTF 2 1-Butyl-3-methylimdazolium bis(trifluoromethylsulfonyl)imide BMINO 3 1-Butyl-3-methylimdazolium nitrate…”
Section: Abbreviated Namesmentioning
confidence: 99%
See 1 more Smart Citation
“…Full names MMIBF 4 1,3-Dimethylimdazolium tetrafluoroborate BMIBF 4 1-Butyl-3-methylimdazolium tetrafluoroborate HMIBF 4 1-Hexyl-3-methylimdazolium tetrafluoroborate BMMIBF 4 1-Butyl-2,3-dimethylimdazolium tetrafluoroborate HOMIBF 4 1-(2'-Hydroxylethyl)-3-methylimdazolium tetrafluoroborate BMIPF 6 1-Butyl-3-methylimdazolium hexafluorophosphate BMINTF 2 1-Butyl-3-methylimdazolium bis(trifluoromethylsulfonyl)imide BMINO 3 1-Butyl-3-methylimdazolium nitrate…”
Section: Abbreviated Namesmentioning
confidence: 99%
“…RTILs have been receiving increasing attention in recent years because of their low volatility, high polarity, ease of recycling, and high thermal stability compared to those of common solvents [1][2][3]. They have therefore been proposed as "green solvents" for chemical reactions and separation processes [4][5][6].…”
mentioning
confidence: 99%
“…Their structural threedimensional organization reveals one major aspect of these salts: they display structural directionality mainly due to hydrogen bonds. 13,14 The net result is a nano-organization of inclusion compounds through ionic-pairing where the IL itself acts as an entropic driver forming a supramolecular network (aggregate formation), i.e., the so called "ionic liquid effect". It is worth highlighting that the organization is spontaneous and of considerable extension, therefore, the effect is expected to be amplified due to the supramolecular aggregate formation rather than based only on the isolated cation or anion.…”
Section: Introductionmentioning
confidence: 99%
“…BMIM BF 4 is composed of 1-butyl-3-methyl imidazolium (cations) and BF 4 (anions). In water solution, because of hydrogenbonding structure between imidazolium cations and BF 4 anions and π-π interaction of imidazole rings, hydrogenbonded nanostructures might present, which contain hydrophobic domains (alkyl chains) and hydrophilic domains (ions) [46]. Therefore, IMPs might be solubilized by the hydrogen-bonded nanostructures through hydrophobic, ionic, and π-π interactions.…”
Section: Effect Of Additives On Solubilizing Abilitymentioning
confidence: 99%