2007
DOI: 10.1590/s0100-40422007000200047
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Diagramas de Ellingham e de Van't Hoff: algumas considerações

Abstract: ELLINGHAM AND VAN'T HOFF DIAGRAMS: SOME CONSIDERATIONS. The main subject of this article is to show the parallelism betwen the Ellingham and Van't Hoff diagrams. The first one is a graphic representation of the changes in the standard Gibbs free energy (Δ r G θ ) as a function of T and was introduced by Ellingham in 1944, in order to study metallurgic processes involving oxides and sulphides. On the other hand, the Van't Hoff diagram is a representation of the function ln K versus (1/T). The equivalence betwee… Show more

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Cited by 6 publications
(4 citation statements)
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“…The polyethylene glycol solutions were prepared according to Villela, Doni-Filho, & Sequeira (1991), while those of mannitol according to the equation established by Van't Hoff (Simoni & Chagas, 2007). The experimental design was completely randomized, with treatments distributed in a factorial 6 × 2 (potential osmotic x batches), with four replicates of 25 seeds, evaluated separately in each osmotic agent.…”
Section: Methodsmentioning
confidence: 99%
“…The polyethylene glycol solutions were prepared according to Villela, Doni-Filho, & Sequeira (1991), while those of mannitol according to the equation established by Van't Hoff (Simoni & Chagas, 2007). The experimental design was completely randomized, with treatments distributed in a factorial 6 × 2 (potential osmotic x batches), with four replicates of 25 seeds, evaluated separately in each osmotic agent.…”
Section: Methodsmentioning
confidence: 99%
“…Two trials were carried out to simulate water deficit during the germination process. To do this, the seeds were submitted to different osmotic potentials induced by mannitol and polyethylene glycol (PEG 6000), solutions of which were prepared as per the Van't Hoff formula (SIMONI;CHAGAS, 2007) and the table proposed by Villela et al (1991) respectively.…”
Section: Methodsmentioning
confidence: 99%
“…A função ΔG (T), não havendo mudança de fase, quando representada graficamente comporta-se como uma reta, 36 -] e os silanóis e, portanto, espacialmente mais afastada, justificando os comportamentos diferenciados dos líquidos iônicos estudados. Neste último caso, a maior disponibilidade de espaços vazios intermoleculares facilitaria a permeação e fixação das moléculas de dióxido de carbono.…”
Section: (9)unclassified