The effect of Zn addition on the microstructures and mechanical behaviors of as-cast Mg-2.5Y-1Ce-0.5Mn alloy was investigated. Microstructure observation demonstrated that with the addition of 1wt%, 3wt% and 5wt% Zn, the ternary phases of LPSO phase, LPSO phase +W-phase and W-phase +T-phase (Mg-Zn-Ce) are precipitated orderly, and the volume fraction of eutectic phases increases. The results of tensile tests demonstrated that with increasing Zn addition, the yield strength s YS ( )of as-cast alloys increases continuously while the ultimate tensile strength s UTS ( )and elongation d ( ) increase nonlinearly. Based on the analysis of microstructure, nanoindentation results and deformation surfaces, it found that the s YS is increased by the increased volume fraction of hard ternary phases. The largest d in 1wt% Zn alloy is contributed from the LPSO phase with an excellent plastic accommodation while the insufficient accommodated role of LPSO phase and the easily broken W-phase deteriorate the ductility of 3wt% Zn alloy. The hard and brittle T-phase also damages the ductility, while the fine grains contribute to the moderate elongation in 5wt% Zn alloy. The s UTS mainly arises from a sustainable increase of strain hardening ability after yielding that associated with both the high yielding point and excellent ductility.