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Cited by 32 publications
(13 citation statements)
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References 22 publications
(21 reference statements)
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“…The gel content increases with the increase of silane concentration. These results are in agreement with those obtained by other researchers 14,16,33 . There are evidences that high concentrations of silane grafted polyethylene are obtained using low concentrations of peroxide or with the increasing of peroxide concentration using low concentrations of silane.…”
Section: Evidence For Grafting and Crosslinking Reactionssupporting
confidence: 94%
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“…The gel content increases with the increase of silane concentration. These results are in agreement with those obtained by other researchers 14,16,33 . There are evidences that high concentrations of silane grafted polyethylene are obtained using low concentrations of peroxide or with the increasing of peroxide concentration using low concentrations of silane.…”
Section: Evidence For Grafting and Crosslinking Reactionssupporting
confidence: 94%
“…The main features of the products obtained are described below. Figure 1 shows the mechanism leading to the crosslinking of polyethylene and the involved reactions 14,[18][19][20][29][30][31] . The changes in the content of structures I-III and the occurrence of oxidation products, whose absorption bands are reported in Table 2 are often used to monitor the crosslinking process In this work, FTIR technique was used to ensure that silane grafting and crosslinking reaction ocurred as a result of the Sioplas process.…”
Section: Resultsmentioning
confidence: 99%
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“…Because PE molecular chain with free radical possesses high reaction activity, crosslinking reaction takes place and inter-molecular chemical bonds generate, when the molecular chain free radicals meet each other. The mechanism of crosslinking reaction is as follows [19]:…”
Section: Introductionmentioning
confidence: 99%
“…Selecting NP-binding metalorganic compounds with similar chemistries and polarities of that of the polymer matrix material such as vinyltriethoxysilane (VTES) or vinyltrimethoxysilane (VTMS) or any analogue of such compounds could be another potential approach (Melo, Aguiar, & Marques, 2015). Due to their chemical similarity and polarity, they can mix effectively in the polymer matrix without significant disturbance to their extensive linkage, thereby minimally affecting their mechanical and barrier properties which mainly depend on the extensive polymer-polymer linkages and crystallinity.…”
Section: Accepted Manuscript 22mentioning
confidence: 99%