1996
DOI: 10.1149/1.1836471
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Abstract: Electrodeposition of copper and nickel on a variety of substrates including conductive polymer films with two different compositions has been studied. The enhancement of the copper and nickel electrodeposition rate was observed for composite polypyrrole films with cation-exchange properties in comparison to undoped polypyrrole films with anionexchange properties. Significant enhancement of the nickel electrodeposition rate on both types of conductive polymer vs. the bare gold electrode was also found. An expla… Show more

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Cited by 95 publications
(22 citation statements)
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“…This has been found to occur for the deposition of Pt in PPY [129,132], PANI [109], and PTHI [88], of Pd in PPY [149] and PANI [10], and of Cu in PPY [168]. If, however, sulfonated PPY is involved in the metal reduction of cationic species (Cu 2þ ) (instead of pristine PPY), a more uniform distribution of the metal phase inside the PPY-PSS layer is found due to the doping role that the metal cations take in this situation [168]. There are few examples showing comparisons of the spatial distribution of the metal component when using alternative metal-deposition techniques.…”
Section: Spatial Distribution Of Electrodeposited Metal Particlesmentioning
confidence: 89%
“…This has been found to occur for the deposition of Pt in PPY [129,132], PANI [109], and PTHI [88], of Pd in PPY [149] and PANI [10], and of Cu in PPY [168]. If, however, sulfonated PPY is involved in the metal reduction of cationic species (Cu 2þ ) (instead of pristine PPY), a more uniform distribution of the metal phase inside the PPY-PSS layer is found due to the doping role that the metal cations take in this situation [168]. There are few examples showing comparisons of the spatial distribution of the metal component when using alternative metal-deposition techniques.…”
Section: Spatial Distribution Of Electrodeposited Metal Particlesmentioning
confidence: 89%
“…[66 to 77]) partly combined with more structure-sensitive methods like confocal laser scanning microscopy [78], laser Raman spectroscopy [79] or electrochemical quartz microbalance [80]. Some authors used STM [3, 77, 81 to 84] or AFM [85,86] to monitor the influence of additives on the deposition; model systems like Cu on single-crystalline Au or Pt were used in these studies.…”
Section: Cu Deposition In the Presence Of Plating Additivesmentioning
confidence: 99%
“…Magnetic metals such as Co, Ni, Gd, and Sm can also be grown on conductive polymers in order to impart magnetic properties. Such composite materials are used in quantum electronics and nanocatalysis [10][11][12][13][14].…”
Section: Introductionmentioning
confidence: 99%
“…Furthermore, it is possible to use a conductive polymer as the substrate for metal reduction. The deposition of metals on polymers strongly depends on the properties of the polymer films and the metal-polymer interactions [8][9][10][11][12][13][14][15][16][17][18].…”
Section: Introductionmentioning
confidence: 99%