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citations
Cited by 16 publications
(9 citation statements)
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References 2 publications
(2 reference statements)
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“…solubility). Third, the regular distribution of variously sized Pd clusters (for instance, the even-odd law) implies that they probably adopt similar structures as ones reported previously (see Table S1)11121314151617181920222324252627282930313233343536373839404142434445. Single crystal X-ray crystallography of [Pd(SC 2 H 4 Ph) 2 ] 6 demonstrate that six palladium atoms arranged in an approximately hexagonal ring, with six bridging sulfur atoms above and six below the plane (see Fig.…”
Section: Resultssupporting
confidence: 69%
See 1 more Smart Citation
“…solubility). Third, the regular distribution of variously sized Pd clusters (for instance, the even-odd law) implies that they probably adopt similar structures as ones reported previously (see Table S1)11121314151617181920222324252627282930313233343536373839404142434445. Single crystal X-ray crystallography of [Pd(SC 2 H 4 Ph) 2 ] 6 demonstrate that six palladium atoms arranged in an approximately hexagonal ring, with six bridging sulfur atoms above and six below the plane (see Fig.…”
Section: Resultssupporting
confidence: 69%
“…Although tiara-like nickel complexes based on diverse thiolate ligands ([Ni(SR) 2 ] n with n = 4 ~ 6, 8 ~ 12111213141516171819222324252627282930313233343536373839) have been prepared (Table S1), only two sizes of Pd clusters ([Pd(SR) 2 ] 6 18204041424344 and [Pd(SR) 2 ] 8 2045) and one Pt cluster ([Pt(SCH 2 COOMe) 2 ] 8 45) have been reported. Additional questions that naturally arise include: Are there any other sized Pd (Pt) clusters beside the reported [Pd(SR) 2 ] 6 18204041424344 and [Pd(SR) 2 ] 8 2045 ([Pt(SCH 2 COOMe) 2 ] 8 45)?…”
mentioning
confidence: 99%
“…15,[18][19][20][21] Tiara-like nickel complexes have received considerable attention resulting in the preparation of complexes with a variety of ring sizes [Ni(-SR) 2 ] n (n = [4][5][6][8][9][10][11][12]. 15,[17][18][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34][35] In contrast, although several tiara-like hexanuclear palladium complexes have been reported, 9,14,19,[36][37][38][39][40][41][42][43] only one octanuclear complex, i.e., [Pd(-S n Pr) 2 ] 8 , is known, and was obtained as a mixture with hexanuclear [Pd(-S n Pr) 2 ] 6 . 19 For platinum, infinite thiolates and selenolates [Pt(-ER) 2 ] ∞ (E = S, Se) have been synthesized using a solvothermal method; …”
Section: Introductionmentioning
confidence: 99%
“…36 In the case of 1, n is odd and a compromise geometry must be adopted, as illustrated in Fig. 24,25,[27][28][29][30]35,37,[47][48][49][50]53,54,56,57 It is obvious that the average values for Ni-S bond lengths are statistically equivalent, while the mean Ni⋯Ni distances vary with the size of the ijNiIJμ-SR) 2 ] n tiaras. The five EDT groups all act as chelating ligands, but bridge the nickel atoms in two different modes, which can be described as the hypothetical units ijNiIJEDT) 2 ] 2− (Fig.…”
Section: View Article Onlinementioning
confidence: 99%
“…In order to make a comparative analysis of the crystal structures, we have made a brief list of the structural parameters of complexes 1, 2, 4-6 and some other tiara-like ijNiIJμ-SR) 2 ] n cyclic structures (Table 1). 24,25,[27][28][29][30]35,37,[47][48][49][50]53,54,56,57 It is obvious that the average values for Ni-S bond lengths are statistically equivalent, while the mean Ni⋯Ni distances vary with the size of the ijNiIJμ-SR) 2 ] n tiaras. The mean Ni⋯Ni distances (from 2.67 to 3.21 Å) increase systematically with increasing nuclear number n (from tetra to dodenuclear).…”
Section: Crystengcomm Papermentioning
confidence: 99%