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Cited by 1,027 publications
(972 citation statements)
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References 23 publications
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“…(In the cases of n odd, this rule is not fully satisÿed.) Besides their regular structures the low-T phases have di usivity as small as that of bulk ice [14], which indicates that the 'ice' nanotubes are indeed solids or solid-like.…”
Section: Model Systemmentioning
confidence: 98%
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“…(In the cases of n odd, this rule is not fully satisÿed.) Besides their regular structures the low-T phases have di usivity as small as that of bulk ice [14], which indicates that the 'ice' nanotubes are indeed solids or solid-like.…”
Section: Model Systemmentioning
confidence: 98%
“…The process is to drive the system to the pentagonal phase, because at the phase equilibrium P N exerted by the pentagonal portion is higher than that by the square portion. A more precise explanation is given by the Clapeyron equations for the quasi-one-dimensional system [15] by which one can obtain the rates of the boundary shift, (@P eq zz =@R) T and (@T eq =@R) Pzz . Indeed MD simulations at R =14:2 have shown the shift of the phase boundaries that is consistent with prediction from the Clapeyron equations.…”
Section: Phase Diagrammentioning
confidence: 99%
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“…32−35 Liquid water inside a SW-CNT can diffuse along the axial direction at room temperature (with typical diffusion constant D of ~10 −5 cm 2 s −1 ), while far below the room temperature, the axial diffusion constant of quasi-one-dimensional (Q1D) solid water, e.g., ice nanotubes, is about 10 −10 cm 2 s −1 . 33,36 It is known that ice nanotubes consist of polygonal water prisms. Can the polygonal water prisms trap one or more H 2 molecules to form H 2 clathrate structures?…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3][4][5][6][7][8][9][10][11] Inside a one-dimensional channel of carbon nanotubes, for example, water molecules could undergo unconventional phase transitions [12][13] and form ice-like structures at room temperatures depending on the channel diameter. Also, a delicate balance between entropy and enthalpy can render these confined water thermodynamically more stable than the bulk water.…”
Section: Introductionmentioning
confidence: 99%