Search citation statements

Order By: Relevance

Paper Sections

Select...
3
1

Citation Types

0
4
0

Year Published

1990
1990
2013
2013

Publication Types

Select...
4
2
1

Relationship

0
7

Authors

Journals

citations
Cited by 31 publications
(4 citation statements)
references
References 0 publications
0
4
0
Order By: Relevance
“…The mixture of dilute acetonitrile solutions of the iodide of CpFeCp-CH 2 -Py + and of (Bu 4 N) 2 M 6 O 19 (M = Mo, W) at 60 °C resulted in brown-yellow solutions, indicating that the electronic interaction between the cationic ferrocenyl donor and the polyoxometalate acceptor has occurred. , On slow evaporation (1 or 2 days) of the solvent, intensely colored crystals were formed according to 2:1 stoichiometry, 2 CpFeCp - CH 2 - Py + normalI + false( NBu 4 false) 2 false[ normalM 6 normalO 19 false] false[ CpFeCp - CH 2 - Py + false] 2 false[ normalM 6 normalO 19 false] 2 + 2 NBu 4 + normalI Similar treatment of acetonitrile solutions of the iodide of CpFeCp-CH 2 -Py + and of (NBu 4 ) 4 W 10 O 32 afforded strongly colored crystals of 4:1 salts, 4 CpFeCp - CH 2 - Py + normalI + false( NBu 4 false) 4 false[ normalW 10 normalO 32...…”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…The mixture of dilute acetonitrile solutions of the iodide of CpFeCp-CH 2 -Py + and of (Bu 4 N) 2 M 6 O 19 (M = Mo, W) at 60 °C resulted in brown-yellow solutions, indicating that the electronic interaction between the cationic ferrocenyl donor and the polyoxometalate acceptor has occurred. , On slow evaporation (1 or 2 days) of the solvent, intensely colored crystals were formed according to 2:1 stoichiometry, 2 CpFeCp - CH 2 - Py + normalI + false( NBu 4 false) 2 false[ normalM 6 normalO 19 false] false[ CpFeCp - CH 2 - Py + false] 2 false[ normalM 6 normalO 19 false] 2 + 2 NBu 4 + normalI Similar treatment of acetonitrile solutions of the iodide of CpFeCp-CH 2 -Py + and of (NBu 4 ) 4 W 10 O 32 afforded strongly colored crystals of 4:1 salts, 4 CpFeCp - CH 2 - Py + normalI + false( NBu 4 false) 4 false[ normalW 10 normalO 32...…”
Section: Resultsmentioning
confidence: 99%
“…The mixture of dilute acetonitrile solutions of the iodide of CpFeCp-CH 2 -Py þ and of (Bu 4 N) 2 M 6 O 19 (M= Mo, W) at 60 °C resulted in brown-yellow solutions, indicating that the electronic interaction between the cationic ferrocenyl donor and the polyoxometalate acceptor has occurred. 27,28 On slow evaporation (1 or 2 days) of the solvent, intensely colored crystals were formed according to 2:…”
Section: Resultsmentioning
confidence: 99%
“…Polyoxometalate acid dissolved in an organic donor solvent induces a sizable red-shift in the charge-transfer absorption spectrum of the polyanion, indicating that the electronic interaction between the organic substrate and the inorganic anion has occured which results in a color change of the solution 14a, However by the introduction of a basic function, such as an amino group in the organic moiety, it is easy to separate the powder salt of the polyoxometalate. 5c, Among several organic substrates, HMPA was chosen due to its strong polarity. When the heteropolytungstate, α- H 4 SiW 12 O 40 · n H 2 O, solution was mixed with HMPA, a new material far less soluble in water than either of the components was precipitated from the solution.…”
Section: Resultsmentioning
confidence: 99%
“…[19a,21b] Alkane oxidation using aldehydes as reducing agents was reported by Murahashi et al, who attempted the aerobic oxidation of cyclohexane and adamantane by ruthenium or iron catalysts in the presence of acetaldehyde. [21a-21c] There have been several reports on the photo-oxidations of alkanes with O 2 catalyzed by polyoxotungstates, [22] heteropolyoxometalates, [23] and FeCl 3 . [24] Shul'pin et al carried out the vanadium-catalyzed oxidation of alkanes to alcohols, ketones, and hydroperoxides by O 2 in combination with H 2 O 2 .…”
Section: Alkane Oxidations With Molecular Oxygenmentioning
confidence: 99%