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Cited by 16 publications
(3 citation statements)
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“…A wide variety of classical as well as new approaches for incorporating alkynyl moieties into organic framework (formation of Csp–Csp, Csp–Csp 2 , Csp–Csp 3 , etc bonds) have appeared in the literature . This includes, but is not limited to, Hay, , Eglinton-Galbraith, Cadiot-Chodkiewicz, Sonogashira, Stille, Negishi, Kumada-Corriu, Grignard, Fritsch-Buttenberg-Wiechell (FBW) rearrangement, and others. Scheme depicts some well-known protocols developed for the synthesis of symmetrical and asymmetrical alkynyl compounds starting from terminal alkynes. Classically, to introduce ethynyl moieties as substituents onto an aliphatic chain/aromatic ring and to synthesize a polymeric material, a sequence of metal-catalyzed Sonogashira, Stille, Hagihara, Negishi, or Kumada coupling reactions are used.…”
Section: Synthesismentioning
confidence: 99%
“…A wide variety of classical as well as new approaches for incorporating alkynyl moieties into organic framework (formation of Csp–Csp, Csp–Csp 2 , Csp–Csp 3 , etc bonds) have appeared in the literature . This includes, but is not limited to, Hay, , Eglinton-Galbraith, Cadiot-Chodkiewicz, Sonogashira, Stille, Negishi, Kumada-Corriu, Grignard, Fritsch-Buttenberg-Wiechell (FBW) rearrangement, and others. Scheme depicts some well-known protocols developed for the synthesis of symmetrical and asymmetrical alkynyl compounds starting from terminal alkynes. Classically, to introduce ethynyl moieties as substituents onto an aliphatic chain/aromatic ring and to synthesize a polymeric material, a sequence of metal-catalyzed Sonogashira, Stille, Hagihara, Negishi, or Kumada coupling reactions are used.…”
Section: Synthesismentioning
confidence: 99%
“…[ 15 ] Cu (II) porphyrin‐catalyzed oxidative coupling of terminal alkynes forming C(sp)—C(sp) bond was also achieved in 2016. [ 16 ] Tetrakis(ethoxycarbonyl)porphyrin (TECP) is an electron‐deficient porphyrin with a flat plane and its manganese complex is an excellent catalyst in the oxidation reaction. [ 17 ] Recently, we found copper and iron TECP complexes showed excellent activity in the construction of C(sp 3 )—O bonds via coupling carboxylic acid and sp 3 C—H bond.…”
Section: Introductionmentioning
confidence: 99%
“…Some heterogeneous catalysts, like silica/chitosan core–shell hybrid‐microsphere‐supported CuI, copper nanoparticles supported on silica coated maghemite, copper immobilized on functionalized silica, polymer‐supported copper, Cu(I) immobilized on functionalized SBA‐15, immobilized copper in MCM‐41, mesoporous silica‐supported copper, copper immobilized on nano‐silica triazine dendrimer, copper‐impregnated magnetite have also been successfully employed to promote this reaction. In 2016, Sheng et al reported that copper porphyrin acted as an efficient catalyst with high TON . Diaziridinone and 3,4‐dihalo‐2(5 H )‐furanones have been investigated as oxidants for this transformation.…”
Section: Introductionmentioning
confidence: 99%