Pd-porphyrin complex-catalyzed allylation of indole with allylic alcohols through C3–C2 coupling

Atia, Alaa A.; Kimura, Masanari

doi:10.1016/j.tet.2021.132213

Tetrahedron

2021

DOI: 10.1016/j.tet.2021.132213

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Pd-porphyrin complex-catalyzed allylation of indole with allylic alcohols through C3–C2 coupling

Alaa A. Atia

Masanari Kimura

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2023

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Cited by 3 publications

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2,3′‐Bisindole Synthesis fromo‐(2.2‐Dibromovinyl)aniline ando‐Ethynylaniline

Yang

Song

et al. 2023

Asian J Org Chem

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A Pd‐catalyzed coupling reaction from o‐alkynylanilines and o‐(2,2‐dibromovinyl)anilines for the synthesis of 2,3′‐bisindoles is developed. In which, o‐ethynylaniline was used as 3‐functionalized indole precursor and o‐(2,2‐dibromovinyl)aniline was used as 2‐functionalized indole precursor. This protocol exhibits high efficiency, good functional group tolerance and scalability from easily accessible starting materials.

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2,3′‐Bisindole Synthesis fromo‐(2.2‐Dibromovinyl)aniline ando‐Ethynylaniline

Yang

Song

et al. 2023

Asian J Org Chem

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Recent advancements review Suzuki and Heck reactions catalyzed by metalloporphyrins

Ghadiri

Farhang

Hassani

et al. 2023

Inorganic Chemistry Communications

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B(3,4,5-F₃H₂C₆)₃Lewis acid-catalysed C3-allylation of indoles

et al. 2023

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Pd-porphyrin complex-catalyzed allylation of indole with allylic alcohols through C3–C2 coupling

Cited by 3 publications

References 42 publications

2,3′‐Bisindole Synthesis fromo‐(2.2‐Dibromovinyl)aniline ando‐Ethynylaniline

2,3′‐Bisindole Synthesis fromo‐(2.2‐Dibromovinyl)aniline ando‐Ethynylaniline

Recent advancements review Suzuki and Heck reactions catalyzed by metalloporphyrins

B(3,4,5-F₃H₂C₆)₃Lewis acid-catalysed C3-allylation of indoles

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Pd-porphyrin complex-catalyzed allylation of indole with allylic alcohols through C3–C2 coupling

Cited by 3 publications

References 42 publications

2,3′‐Bisindole Synthesis fromo‐(2.2‐Dibromovinyl)aniline ando‐Ethynylaniline

2,3′‐Bisindole Synthesis fromo‐(2.2‐Dibromovinyl)aniline ando‐Ethynylaniline

Recent advancements review Suzuki and Heck reactions catalyzed by metalloporphyrins

B(3,4,5-F3H2C6)3Lewis acid-catalysed C3-allylation of indoles

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Product

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B(3,4,5-F₃H₂C₆)₃Lewis acid-catalysed C3-allylation of indoles