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Cited by 42 publications
(26 citation statements)
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“…However, precipitate was formed with a lag phase ranging for up to 2 hours depending on the degree of supersaturation. The speciation of calcium in these supersaturated solutions depends on the chemical equilibria of eqn (8) and (9). Since citrate has a thermodynamic association constant of 3.6 Â 10 4 at 25 C for binding calcium compared to 49 for lactate, citrate can be assumed to control the free calcium ion concentration.…”
Section: Resultsmentioning
confidence: 99%
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“…However, precipitate was formed with a lag phase ranging for up to 2 hours depending on the degree of supersaturation. The speciation of calcium in these supersaturated solutions depends on the chemical equilibria of eqn (8) and (9). Since citrate has a thermodynamic association constant of 3.6 Â 10 4 at 25 C for binding calcium compared to 49 for lactate, citrate can be assumed to control the free calcium ion concentration.…”
Section: Resultsmentioning
confidence: 99%
“…The thermodynamic association constants are valid for ion activities as they were determined by extrapolation to zero ionic strength. 9,15 For the supersaturated solutions with ionic strength higher than unity concentration based association constants will have to replace the activity based association constants for quantitative calculations. The use of equilibrium constants determined for 1.0 M KCl or NaCl seems an acceptable approximation, since ionic strength in most of the supersaturated and the equilibrated solutions are close to unity.…”
Section: Resultsmentioning
confidence: 99%
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