Synthesis and characterization of mixed ligand cyclopalladates with 2-phenylpyridine and substituted phenanthrolines: Investigation into the hydroxylation reaction of 2-phenylpyridine

Garypidou, Antonia; Ypsilantis, Konstantinos; Tsolis, Theodoros; Kourtellaris, Andreas; Plakatouras, John C.; Garoufis, Achilleas

doi:10.1016/j.ica.2021.120254

Cited by 3 publications

(1 citation statement)

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“…In general, ligands that exhibit the ( N , O ) binding mode, such as 8-hydroxyquinolines or 2-picolinates, tend to form highly stable half-sandwich Ru or Rh complexes; 39–41 however, the 2-(pyridin-2-yl)phenolate-type ligands form a six-membered chelate ring, which is not favored. The crystal structures of Pd( ii ), Cu( ii ) and half-sandwich Rh( iii ) complexes with similar ligands showed rotation around the C–C bond connecting the two aromatic rings, resulting in a significant deviation from a planar structure; 42–45 this most probably contributes to the decreased stability compared to the complexes formed with bpy-type ligands.…”

Section: Resultsmentioning

confidence: 99%

Organometallic Ru(ii), Rh(iii) and Re(i) complexes of sterane-based bidentate ligands: synthesis, solution speciation, interaction with biomolecules and anticancer activity

Pivarcsik,

Kiss,

Rapuš

et al. 2024

Dalton Trans.

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Section: Resultsmentioning

confidence: 99%

Organometallic Ru(ii), Rh(iii) and Re(i) complexes of sterane-based bidentate ligands: synthesis, solution speciation, interaction with biomolecules and anticancer activity

Pivarcsik,

Kiss,

Rapuš

et al. 2024

Dalton Trans.

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Synthesis, characterization and photophysical properties of mixed ligand cyclometalated platinum(II) complexes containing 2-phenylpyridine and pyridine carboxylic acids

et al. 2023

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Pd(II), Pd(III) and Pd(IV) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 44 Years (1980–2023) of NMR and Single Crystal X-ray Studies

Pazderski,

Abramov

2023

Crystals

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In this paper, a review on Pd(II), Pd(III), and Pd(IV) cyclometallated compounds with 2-arylpyridines (2-phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2-phenylsulfanylpyridine, 2-anilinopyridine, 2-(naphth-1-yl)pyridine, 2-(naphth-2-yl)pyridine, and their derivatives) and their analogues (2-phenylquinoline and 7,8-benzoquinoline) with 174 references is presented. A total of 672 species, containing κ2-N(1),C(6′)*-palladium (Pd(II), Pd(III), Pd(IV)) or analogous moiety (i.e., chelated by nitrogen of the pyridine-like ring and the deprotonated ortho-carbon of the phenyl-like ring) and thus possessing a character intermediate between metal complexes and organometallics, studied in the years 1980–2023 by NMR spectroscopy and/or single crystal X-ray diffraction (202 X-ray structures, for 186 species), are described. The biological or catalytic activity and luminescence properties of these species, as well as their possible applications as advanced materials were studied and are also quoted.

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Synthesis and characterization of mixed ligand cyclopalladates with 2-phenylpyridine and substituted phenanthrolines: Investigation into the hydroxylation reaction of 2-phenylpyridine

Cited by 3 publications

References 61 publications

Organometallic Ru(ii), Rh(iii) and Re(i) complexes of sterane-based bidentate ligands: synthesis, solution speciation, interaction with biomolecules and anticancer activity

Organometallic Ru(ii), Rh(iii) and Re(i) complexes of sterane-based bidentate ligands: synthesis, solution speciation, interaction with biomolecules and anticancer activity

Synthesis, characterization and photophysical properties of mixed ligand cyclometalated platinum(II) complexes containing 2-phenylpyridine and pyridine carboxylic acids

Pd(II), Pd(III) and Pd(IV) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 44 Years (1980–2023) of NMR and Single Crystal X-ray Studies

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