“…Among these, rutile is the thermodynamically most stable phase at ambient conditions, whereas anatase and brookite are stable at low temperature. – Major technological applications of these materials include pigments, plastics, cosmetics, electronics, and catalytic industries. Notably, the anatase phase has been used in photocatalysts, dye-sensitized solar cells, gas sensors, and biomedicine. – Functional anatase nanoparticles, tuned either in particle size or shape, have enhanced photocatalytic effect and larger band gap energy than in bulk state. , Pressure is another means to control the size and shape of a solid both in microscopic and atomistic scale and, hence, can give rise to corresponding property changes. To form a basis of pressure-dependent property tunability of various functional nanoparticles, we have investigated two shape-contrasting anatase nanoparticles along with a bulk sample using monochromatic synchrotron X-ray and a diamond-anvil cell.…”