2019
DOI: 10.1002/adma.201807178
|View full text |Cite
|
Sign up to set email alerts
|

Abstract: In the continuously growing field of correlated electronic molecular crystals, there is significant interest in addressing alkali-metal-intercalated aromatic hydrocarbons, in which the possibility of hightemperature superconductivity emerges. However, searching for superconducting aromatic molecular crystals remains elusive due to their small shielding fraction volume. To exploit this potential, a design principle for percolation networks of technologically important film geometry is indispensable. Here we sho… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1
1

Citation Types

0
6
0

Year Published

2019
2019
2024
2024

Publication Types

Select...
6

Relationship

2
4

Authors

Journals

citations
Cited by 11 publications
(6 citation statements)
references
References 38 publications
0
6
0
Order By: Relevance
“…Inspired by this feature, poly- p -phenylene (PPP), an organic phenyl system with a porous network structure composed of C and H, is also expected to be used as electrode materials for PIBs. The structures and fabrications of K-intercalated PPPs have been studied preliminarily. Previous studies showed that the K-intercalated PPP can be obtained by the solid-state reaction between pure potassium lumps and PPP sealed in glass tubes under high-vacuum conditions. , In this paper, therefore, we study K-intercalated PPP to examine the feasibility of PPP as the anode of PIBs, based on the first-principles calculations. Selected two typical systems of PPPs, biphenyl (C 12 H 10 ) and p -terphenyl (C 18 H 14 ), the K-intercalated structure, specific capacity, diffusion barrier, and electrical conductivity were analyzed.…”
Section: Introductionmentioning
confidence: 99%
“…Inspired by this feature, poly- p -phenylene (PPP), an organic phenyl system with a porous network structure composed of C and H, is also expected to be used as electrode materials for PIBs. The structures and fabrications of K-intercalated PPPs have been studied preliminarily. Previous studies showed that the K-intercalated PPP can be obtained by the solid-state reaction between pure potassium lumps and PPP sealed in glass tubes under high-vacuum conditions. , In this paper, therefore, we study K-intercalated PPP to examine the feasibility of PPP as the anode of PIBs, based on the first-principles calculations. Selected two typical systems of PPPs, biphenyl (C 12 H 10 ) and p -terphenyl (C 18 H 14 ), the K-intercalated structure, specific capacity, diffusion barrier, and electrical conductivity were analyzed.…”
Section: Introductionmentioning
confidence: 99%
“…Usually, alkali metals doped aromatic SCs have low shielding fractions, 122 the highest value of which is 16% for pressed K 3 picene, 118 preventing researchers from determining their structures. In 2011, Wang et al 123 found that Sr 1.5 phenanthrene and Ba 1.5 phenanthrene showed a superconducting transition at 5.6 K and 5.4 K, respectively.…”
Section: Organic Superconductorsmentioning
confidence: 99%
“…Usually, alkali metals doped aromatic SCs have low shielding fractions, 122 the highest value of which is 16%…”
Section: Metal Intercalated Aromatic Hydrogensmentioning
confidence: 99%
“…Based on BCS theory, we can improve the T c by combining the light metal with light‐element hydrides. The mechanism of charge transfer driving the metallization has been proven to be feasible in organic superconductors…”
Section: Conclusion and Future Prospectivementioning
confidence: 99%