The Mizoroki–Heck Reaction 2009
DOI: 10.1002/9780470716076.ch1
|View full text |Cite
|
Sign up to set email alerts
|
Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

1
65
0

Year Published

2013
2013
2020
2020

Publication Types

Select...
5
3

Relationship

0
8

Authors

Journals

citations
Cited by 66 publications
(66 citation statements)
references
References 122 publications
1
65
0
Order By: Relevance
“…With very bulky monophosphines, active species having only one phosphine coordinated to the metal have been proposed [80,82]. In view of the above complexation studies, such mono-ligated intermediates are also likely to be operative with HUGPHOS ligands (Scheme 9).…”
Section: Resultsmentioning
confidence: 99%
“…With very bulky monophosphines, active species having only one phosphine coordinated to the metal have been proposed [80,82]. In view of the above complexation studies, such mono-ligated intermediates are also likely to be operative with HUGPHOS ligands (Scheme 9).…”
Section: Resultsmentioning
confidence: 99%
“…The first mechanistic step in the Heck reaction is oxidative addition of the aryl halide to the Pd(0) catalyst and this can be the rate determining step. 57 The alkene, which is attached to the Si surface, is not involved in the oxidative addition step of the mechanism. Consequently, in the Heck type 2 procedure, the oxidative addition product, which is illustrated in figure 5 (b), is formed separately and then introduced into the Si surface.…”
Section: B-alkyl Suzukimentioning
confidence: 99%
“…Finally, regeneration of the active Pd(0) complex by reductive elimination of hydridopalladium(II) species. [65][66][67] Despite this well-accepted general mechanism, the Heck catalytic reaction can involve different types of Pd(0) and Pd(II) intermediates, whose structure and reactivity vary depending on the experimental conditions, the catalytic precursors (e.g., whether they are Pd(0) complexes, Pd(OAc) 2 , or palladacycles), the types of ligands (e.g., mono-or bisphosphines, carbenes, and bulky monophosphines), and any possible additives (e.g., halides and acetates) used in the reaction. 65 Furthermore, although there is agreement on the general mechanism of the Heck reaction, there is also still some ambiguity about the mechanism of the Heck reactions catalyzed by heterogeneous catalysts.…”
Section: Mechanisms Of the Heck Coupling Reactionmentioning
confidence: 99%
“…[65][66][67] Despite this well-accepted general mechanism, the Heck catalytic reaction can involve different types of Pd(0) and Pd(II) intermediates, whose structure and reactivity vary depending on the experimental conditions, the catalytic precursors (e.g., whether they are Pd(0) complexes, Pd(OAc) 2 , or palladacycles), the types of ligands (e.g., mono-or bisphosphines, carbenes, and bulky monophosphines), and any possible additives (e.g., halides and acetates) used in the reaction. 65 Furthermore, although there is agreement on the general mechanism of the Heck reaction, there is also still some ambiguity about the mechanism of the Heck reactions catalyzed by heterogeneous catalysts. Nonetheless, mechanistic studies of the Heck reactions catalyzed by supported Pd-based heterogeneous catalysts have led to the conclusion that (1) soluble and catalytic-active palladium species form by leaching from the supported-Pd catalysts and (2) these soluble palladium species then involve in the reactions, and their catalytic activities and readsorption on the solid material play major roles in the overall rates of the catalytic reaction.…”
Section: Mechanisms Of the Heck Coupling Reactionmentioning
confidence: 99%