1,2-Bis(trimethylsilyl)hydrazido Titanium Complexes

Titanium Complexes Containing Bulky η2-1,2,4-Triazolato Ligands

“…[17] Apparently, steric hindrance seems not to be a prerequisite for the formation of the homoleptic species, whereas bulky substituents are important for the stability of the compounds 2Ϫ4. Other titanium complexes with three-membered TiN 2 rings contain η 2 -diazenido, [31] -diazo [32] or -hydrazido [33,34] ligands. Whereas the η 2 -diazenido and -diazo ligands show similar structural features to those of 1, the latter ones are slightly different in that the TiϪN bond lengths in η 2 -hydrazido complexes differ by approx.…”

Titanium Complexes Containing Bulky η2-1,2,4-Triazolato Ligands

“…[17] Apparently, steric hindrance seems not to be a prerequisite for the formation of the homoleptic species, whereas bulky substituents are important for the stability of the compounds 2Ϫ4. Other titanium complexes with three-membered TiN 2 rings contain η 2 -diazenido, [31] -diazo [32] or -hydrazido [33,34] ligands. Whereas the η 2 -diazenido and -diazo ligands show similar structural features to those of 1, the latter ones are slightly different in that the TiϪN bond lengths in η 2 -hydrazido complexes differ by approx.…”

Titanium Complexes Containing Bulky η2-1,2,4-Triazolato Ligands

“…[17] Apparently, steric hindrance seems not to be a prerequisite for the formation of the homoleptic species, whereas bulky substituents are important for the stability of the compounds 2Ϫ4. Other titanium complexes with three-membered TiN 2 rings contain η 2 -diazenido, [31] -diazo [32] or -hydrazido [33,34] ligands. Whereas the η 2 -diazenido and -diazo ligands show similar structural features to those of 1, the latter ones are slightly different in that the TiϪN bond lengths in η 2 -hydrazido complexes differ by approx.…”

Titanium Complexes Containing Bulky η2-1,2,4-Triazolato Ligands

“…[17] Apparently, steric hindrance seems not to be a prerequisite for the formation of the homoleptic species, whereas bulky substituents are important for the stability of the compounds 2Ϫ4. Other titanium complexes with three-membered TiN 2 rings contain η 2 -diazenido, [31] -diazo [32] or -hydrazido [33,34] ligands. Whereas the η 2 -diazenido and -diazo ligands show similar structural features to those of 1, the latter ones are slightly different in that the TiϪN bond lengths in η 2 -hydrazido complexes differ by approx.…”