Unilamellar colloids of graphite oxide (GO) were prepared from natural graphite and were grown as monolayer and multilayer thin films on cationic surfaces by electrostatic selfassembly. The multilayer films were grown by alternate adsorption of anionic GO sheets and cationic poly(allylamine hydrochloride) (PAH). The monolayer films consisted of 11-14 Å thick GO sheets, with lateral dimensions between 150 nm and 9 µm. Silicon substrates primed with amine monolayers gave partial GO monolayers, but surfaces primed with Al 13 O 4 -(OH) 24 (H 2 O) 12 7+ ions gave densely tiled films that covered approximately 90% of the surface. When alkaline GO colloids were used, the monolayer assembly process selected the largest sheets (from 900 nm to 9 µm) from the suspension. In this case, many of the flexible sheets appeared folded in AFM images. Multilayer (GO/PAH) n films were invariably thicker than expected from the individual thicknesses of the sheets and the polymer monolayers, and this behavior is also attributed to folding of the sheets. Multilayer (GO/PAH) n and (GO/ polyaniline) n films grown between indium-tin oxide and Pt electrodes show diodelike behavior, and higher currents are observed with the conductive polyaniline-containing films. The resisitivity of these films is decreased, as expected, by partial reduction of GO to carbon.

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Scanning force microscopy (SFM) was used for probing micromechanical properties of compliant polymeric materials. Classic models of elastic contacts, Sneddon's, Hertzian, and JKR, were tested for various indentation depths and for a variety of polymeric materials. We selected extremely compliant polyisoprene rubbers (Young's modulus, E ) 1-3 MPa), elastic polyurethanes (E ) 5-50 MPa), and hard surfaces of polystyrene (PS) and polyvinylchloride (PVC) (E ) 1-5 GPa). Both Sneddon's and Hertzian elastic models gave consistent and reliable results in the range of indentation depths up to 200 nm which are close to JKR solution. Close correlation is observed between absolute values of elastic moduli determined by SFM and known values for bulk materials.

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