Q switching of a diode-pumped Nd3+:KGd(WO4)2 laser at 1.35 microm by use of cobalt-doped magnesium- and zinc-aluminosilicate glass ceramics as saturable absorbers is demonstrated. Q-switching efficiency up to 40% has been obtained. Ground-state absorption cross sections for Co2+ ions at the wavelengths of 1.35 and 1.54 microm are estimated to be (3.5-4.0) x 10(-19) cm2. Bleaching relaxation times under the excitation of the 4A2 --> 4T1(4F) transition of tetrahedrally coordinated Co2+ ions are of 280 +/- 50 ns and 700 +/- 80 ns for magnesium- and zinc-aluminosilicate glass ceramics, respectively.
A new saturable absorber Q switch for 1.54-mum Er:glass lasers is presented. The saturable absorber is a transparent glass ceramic that contains magnesium-aluminum spinel nanocrystallites doped with tetrahedrally coordinated Co(2+) ions. We obtained Q-switched pulses of up to 5.5 mJ in energy and 80 ns in duration at 1.54 mum. The relaxation time of (4)A(2) ?(4)T(1)((4)F) transition bleaching was measured to be (450 ? 150) ns. Ground-state and excited-state absorption cross sections at 1.54-mum wavelength were estimated to be (3.2 ? 0.4) x 10(-19) cm(2) and (5.0 ? 0.6) x 10(-20) cm(2), respectively.
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