Ozone is widely used for water treatment because of its strong oxidation ability. However, the efficiency of ozone in groundwater remediation is limited because of its relatively low solubility and rapid decomposition in the aqueous phase. Methods for increasing the stability of ozone within the subsurface are drawing increasing attention. Micro-nano-bubbles (MNBs), with diameters ranging from tens of nanometres to tens of micrometres, present rapid mass transfer rates, persist for a relatively long time in water, and transport with groundwater flow, which significantly improve gas concentration and provide a continuous gas supply. Therefore, MNBs show a considerable potential for application in groundwater remediation. In this study, the characteristics of ozone MNBs were examined, including their size distribution, bubble quantity, and zeta potential. The mass transfer rate of ozone MNBs was experimentally investigated. Ozone MNBs were then used to treat organics-contaminated water, and they showed remarkable cleanup efficiency. Column tests were also conducted to study the efficiency of ozone MNBs for organics-contaminated groundwater remediation. Based on the laboratory tests, field monitoring was conducted on a trichloroethylene (TCE)-contaminated site. The results showed that ozone MNBs can greatly improve remediation efficiency and represent an innovative technology for in situ remediation of organics-contaminated groundwater.
Micro-nano bubbles (MNBs) technology has shown great potential in groundwater bioremediation because of their large specific surface area, negatively charged surface, long stagnation, high oxygen transfer efficiency, etc. Groundwater salinity, which varies from sites due to different geological and environmental conditions, has a strong impact on the bioremediation effect. However, the groundwater salinity effect on MNBs’ behavior has not been reported. In this study, the size distribution, oxygen transfer efficiency and zeta potential of MNBs was investigated in different salt concentrations. In addition, the permeability of MNBs’ water through sand in different salt concentrations was studied. The results showed that water salinity has no influence on bubble size distribution during MNBs generation. MNBs could greatly enhance the oxygen transfer efficiency from inner bubbles to outer water, which may greatly enhance aerobic bioremediation. However, the enhancement varied depending on salt concentration. 0.7 g/L was found to be the optimal salt concentration to transfer oxygen. Moreover, MNBs in water salinity of 0.7 g/L had the minimum zeta potential. The correlation of zeta potential and mass transfer was discussed. The hydraulic conductivities of sand were similar for MNBs water with different salt concentrations. The results suggested that salinity had a great influence on MNBs performance, and groundwater salinity should be taken into careful consideration in applying MNBs technology to the enhancement of bioremediation.
The efficiency of ozone for the treatment of organics contaminated wastewater is limited by its slow dissolution rate and rapid decomposition in the aqueous phase. Micro-nano-bubbles (MNBs) are a novel method to prolong the reactivity of the ozone in the aqueous phase, thereby accelerating the treatment of the contaminant. In this study, the effects of pH and salinity on the treatment efficiency of ozone MNBs were examined. The highest efficiency was observed in weak acidic conditions and an increase in salinity enhanced the treatment efficiency significantly. Furthermore, the treatment of highly saline industrial wastewater as well as multi-contaminant groundwater containing persistent organics were also investigated. Treatment using ozone MNBs had a considerable effect on wastewaters that are otherwise difficult to treat using other methods; hence, it is a promising technology for wastewater treatment.
Nowadays groundwater contamination widely spreads in China. Organic pollutants are of the public concern since they are toxic and with long life cycle, causing considerable remediation cost. The innovative remediation technologies are urgently needed. In this paper, the micro-nano bubbles (MNBs) technology with the ozone oxidation method was proposed, and laboratory tests were conducted for both surface water and groundwater remediation to degrade methyl orange, which was selected as the representative pollutant. In the test, deionized water was used to configure methyl orange solution of certain concentration, then the concentrations of methyl orange were monitored during the treatment process of ozone macro bubbles, oxygen MNBs, and ozone MNBs. Glass beads with the diameter of 4.0-4.5 mm were selected to simulate highly permeable soils, and the concentrations of both methyl orange and the dissolved ozone were measured during groundwater remediation process by ozone MNBs. The results indicated that oxygen MNBs did not degrade methyl orange, while the degradation effect of ozone bubbles was obvious. The degradation effect of ozone MNBs can even be 41 times greater than ozone macro bubbles for polluted surface water. The groundwater remediation tests further verified that ozone MNBs have significant capability in the remediation of organic contaminated subsurface.
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